Synthesis of Dimethyl Phenylphosphonates Catalyzed by Group VI Metal(0) Hexacarbonyls


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Abstract

The coupling of dimethyl phosphite and iodobenzene occurs in the presence of catalytic amounts of homoligand carbonyl complexes of chromium subgroup metals to form dimethyl phenylphosphonate in yields of 50–73% depending on the metal.

About the authors

A. I. Kuramshin

Kazan (Volga Region) Federal University

Email: fea_naro@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

A. V. Plotnikova

Kazan (Volga Region) Federal University

Email: fea_naro@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

M. V. Adel’shina

Kazan (Volga Region) Federal University

Email: fea_naro@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

V. I. Galkin

Kazan (Volga Region) Federal University

Author for correspondence.
Email: fea_naro@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

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