Chemical Transformations of Tetracyclo[3.3.1.13,7.01,3]decane (1,3-Dehydroadamantane): VII. Reaction of 1,3-Dehydroadamantane with Alkanediols and Amino Alcohols


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The reaction of 1,3-dehydroadamantane with C2–C6 α,ω-alkanediols selectively afforded ω-(adamantan- 1-yloxy)alkan-1-ols in 87–94% yield. The reaction of 1,3-dehydroadamantane with ω-aminoalkan-1- ols (2-aminoethanol and 3-aminopropan-1-ol) gave mixtures of addition products through the oxygen and nitrogen atoms, which can be readily separated by fractional vacuum distillation or crystallization.

Sobre autores

G. Butov

Volzhsky Polytechnic Institute (Branch); Volgograd State Technical University

Autor responsável pela correspondência
Email: butov@volpi.ru
Rússia, ul. Engel’sa 42a, Volzhsky, Volgograd oblast, 404121; pr. Lenina 28, Volgograd, 400131

V. Mokhov

Volgograd State Technical University

Email: butov@volpi.ru
Rússia, pr. Lenina 28, Volgograd, 400131

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