Some Peculiarities of the Reduction of Di- and Trichlorocyclopentenones

V. A. Egorov; L. S. Khasanova; F. A. Gimalova; I. A. Zagreeva; M. S. Miftakhov

doi:10.1134/S1070428019010159

Some Peculiarities of the Reduction of Di- and Trichlorocyclopentenones

Authors: Egorov V.A.¹, Khasanova L.S.¹, Gimalova F.A.¹, Zagreeva I.A.¹, Miftakhov M.S.¹
Affiliations:
1. Ufa Institute of Chemistry, Ufa Federal Research Center
Issue: Vol 55, No 1 (2019)
Pages: 118-120
Section: Short Communications
URL: https://journal-vniispk.ru/1070-4280/article/view/219771
DOI: https://doi.org/10.1134/S1070428019010159
ID: 219771

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Abstract

The hydrogenation of 5-allyl- and 5-(2-methylbut-3-en-2-yl)-2,3,5-trichlorocyclopentenones in methanol in the presence of 10% Pd/C is accompanied by exhaustive dechlorination with the formation of 3-propyl- and 3-(2-methylbutan-2-yl)cyclopentane-1,2,4-triones.