Email this article Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium
- Authors: Zonov Y.V.1,2, Karpov V.M.1, Mezhenkova T.V.1
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Affiliations:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 55, No 8 (2019)
- Pages: 1103-1111
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/221020
- DOI: https://doi.org/10.1134/S1070428019080086
- ID: 221020
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Abstract
The carbonylation of perfluoro-2-R-benzocyclobutenones (R = F, CF3, C2F5, C6F5) in a CO-SbF5 system is accompanied by transformations of the four-membered cycle in the substrate to form polyfluorinated 1H-isochromene derivatives. The reaction of perfluoro-2-R-benzocyclobutenes (R = F, CF3, C2F5) with (CF3CO)2O or CF3COOH in a SbF5 medium in a sealed ampule involves formation of polyfluorobenzocyclobutenones and their carbonylation under the reaction conditions.
About the authors
Ya. V. Zonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: yzonov@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
V. M. Karpov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: yzonov@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
T. V. Mezhenkova
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: yzonov@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
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