Formyl Derivatives of Amino-Substituted Polyfluorotriphenyl-4,5-dihydro-1 H -pyrazoles: Synthesis and Use as Donor Blocks of Nonlinear Optical Chromophores

V. V. Shelkovnikov; N. A. Orlova; I. Yu. Kargapolova; K. D. Erin; A. M. Maksimov; A. A. Chernonosov

doi:10.1134/S1070428019100087

Formyl Derivatives of Amino-Substituted Polyfluorotriphenyl-4,5-dihydro-1H-pyrazoles: Synthesis and Use as Donor Blocks of Nonlinear Optical Chromophores

作者: Shelkovnikov V.V.¹^,2, Orlova N.A.¹, Kargapolova I.Y.¹, Erin K.D.³, Maksimov A.M.¹, Chernonosov A.A.⁴
隶属关系:
1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
2. Novosibirsk State Technical University
3. Tomsk Polytechnic University
4. Institute of Chemical Biology and Fundamental Medicine, Siberian Branch
期: 卷 55, 编号 10 (2019)
页面: 1504-1517
栏目: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/221256
DOI: https://doi.org/10.1134/S1070428019100087
ID: 221256

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A series of new formyl derivatives of polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles containing various amine residues in the fluorinated benzene ring have been synthesized and used as donor building blocks in the synthesis of donor–acceptor dyes as potential chromophores for nonlinear electro-optics. Effects of substituents in the donor and acceptor moieties of the obtained chromophores on their spectral characteristics have been studied.