Email this article Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine
- Authors: Kuksenok V.Y.1, Shtrykova V.V.1, Filimonov V.D.1, Sidel’nikova S.P.1
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Affiliations:
- National Research Tomsk Polytechnic University
- Issue: Vol 52, No 2 (2016)
- Pages: 196-199
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/213676
- DOI: https://doi.org/10.1134/S1070428016020056
- ID: 213676
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Abstract
Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.
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About the authors
V. Yu. Kuksenok
National Research Tomsk Polytechnic University
Author for correspondence.
Email: vera.kuksenok@mail.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050
V. V. Shtrykova
National Research Tomsk Polytechnic University
Email: vera.kuksenok@mail.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050
V. D. Filimonov
National Research Tomsk Polytechnic University
Email: vera.kuksenok@mail.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050
S. P. Sidel’nikova
National Research Tomsk Polytechnic University
Email: vera.kuksenok@mail.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050
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