Enviar artigo por via de e-mail Efficient one-stage procedure of Beckmann ketones rearrangement in the presence of hydroxylamine
- Autores: Kuksenok V.Y.1, Shtrykova V.V.1, Filimonov V.D.1, Sidel’nikova S.P.1
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Afiliações:
- National Research Tomsk Polytechnic University
- Edição: Volume 52, Nº 2 (2016)
- Páginas: 196-199
- Seção: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/213676
- DOI: https://doi.org/10.1134/S1070428016020056
- ID: 213676
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Resumo
Ketoximes formed from ketones in the presence of hydroxylamine and silica gel in formic acid undergo in situ the Beckmann rearrangement under mild conditions affording in high yields the corresponding amides. Unsymmetrical aromatic ketones, methyl aryl ketones, and methyl cyclohexyl ketone under these conditions form as a rule amides mixtures.
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Sobre autores
V. Kuksenok
National Research Tomsk Polytechnic University
Autor responsável pela correspondência
Email: vera.kuksenok@mail.ru
Rússia, pr. Lenina 30, Tomsk, 634050
V. Shtrykova
National Research Tomsk Polytechnic University
Email: vera.kuksenok@mail.ru
Rússia, pr. Lenina 30, Tomsk, 634050
V. Filimonov
National Research Tomsk Polytechnic University
Email: vera.kuksenok@mail.ru
Rússia, pr. Lenina 30, Tomsk, 634050
S. Sidel’nikova
National Research Tomsk Polytechnic University
Email: vera.kuksenok@mail.ru
Rússia, pr. Lenina 30, Tomsk, 634050
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