Email this article Enantioselective addition of β-keto phosphinate to ω-nitrostyrene in the presence of optically active nickel(II) complex
- Authors: Sibiryakova A.E.1, Reznikov A.N.1, Rybakov V.B.2, Klimochkin Y.N.1
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Affiliations:
- Samara State Technical University
- Lomonosov Moscow State University
- Issue: Vol 53, No 2 (2017)
- Pages: 153-156
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/215725
- DOI: https://doi.org/10.1134/S1070428017020014
- ID: 215725
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Abstract
Synthesis was performed of individual methyl [(S,2R,3S)-4-nitro-1-oxo-1,3-diphenylbutan-2-yl]-(phenyl)phosphinate from racemic β-keto phosphinate and ω-nitrostyrene under the catalysis by nickel(II) complex with (1R,2R)-N,N'-dibenzylcyclohexane-1,2-diamine.
About the authors
A. E. Sibiryakova
Samara State Technical University
Author for correspondence.
Email: hom_92@mail.ru
Russian Federation, Molodogvardeiskaya ul. 244, Samara, 443100
A. N. Reznikov
Samara State Technical University
Email: hom_92@mail.ru
Russian Federation, Molodogvardeiskaya ul. 244, Samara, 443100
V. B. Rybakov
Lomonosov Moscow State University
Email: hom_92@mail.ru
Russian Federation, Moscow
Yu. N. Klimochkin
Samara State Technical University
Email: hom_92@mail.ru
Russian Federation, Molodogvardeiskaya ul. 244, Samara, 443100
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