Enantioselective addition of β-keto phosphinate to ω-nitrostyrene in the presence of optically active nickel(II) complex

A. E. Sibiryakova; A. N. Reznikov; V. B. Rybakov; Yu. N. Klimochkin

doi:10.1134/S1070428017020014

Enantioselective addition of β-keto phosphinate to ω-nitrostyrene in the presence of optically active nickel(II) complex

作者: Sibiryakova A.E.¹, Reznikov A.N.¹, Rybakov V.B.², Klimochkin Y.N.¹
隶属关系:
1. Samara State Technical University
2. Lomonosov Moscow State University
期: 卷 53, 编号 2 (2017)
页面: 153-156
栏目: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/215725
DOI: https://doi.org/10.1134/S1070428017020014
ID: 215725

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详细

Synthesis was performed of individual methyl [(S,2R,3S)-4-nitro-1-oxo-1,3-diphenylbutan-2-yl]-(phenyl)phosphinate from racemic β-keto phosphinate and ω-nitrostyrene under the catalysis by nickel(II) complex with (1R,2R)-N,N'-dibenzylcyclohexane-1,2-diamine.