Email this article Alkyl 3-nitroacrylates: Synthesis and reactions with cyclohexane-1,3-diones and Meldrum’s acid
- Authors: Pelipko V.V.1, Makarenko S.V.1, Baichurin R.I.1, Berestovitskaya V.M.1, Kovalenko K.S.2
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Affiliations:
- Herzen State Pedagogical University of Russia
- Chemical and Food Fragrances Factory Ltd.
- Issue: Vol 53, No 12 (2017)
- Pages: 1799-1808
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/217014
- DOI: https://doi.org/10.1134/S107042801712003X
- ID: 217014
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Abstract
A modified procedure was proposed for the synthesis of alkyl 3-nitroacrylates by nitroiodination of alkyl acrylates and subsequent dehydroiodination of iodonitropropanoates with triethylamine. Alkyl 3-nitroacrylates reacted with cyclohexane-1,3-dione, dimedone, and Meldrum’s acid in the presence of N,N,N-tri-methylanilinium hydroxide (Rodionov’s catalyst) in anhydrous methanol to give the corresponding Michael adducts.
About the authors
V. V. Pelipko
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186
S. V. Makarenko
Herzen State Pedagogical University of Russia
Author for correspondence.
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186
R. I. Baichurin
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186
V. M. Berestovitskaya
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186
K. S. Kovalenko
Chemical and Food Fragrances Factory Ltd.
Email: kohrgpu@yandex.ru
Russian Federation, ul. Partizanskaya 11, St. Petersburg, 195027
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