Reaction of 1,5-diphenyl-3-arylverdazyles with СН-acids


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Resumo

The presence of electron-donor substituents in the phenyl ring at the atom С3 of the tetrazinyl ring increases, and of electron-acceptor substituents reduces the reaction rate of 1,5-diphenyl-3-arylverdazyl radicals with СН-acids. The reaction is described with a kinetic equation of the second order with respect to verdazyl, the process rate is determined by the energy of the electron transfer from the SOMO (singly occupied molecular orbital) of the radical to the LUMO of the СН-acid.

Sobre autores

B. Tanaseichuk

Mordovian State University

Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005

O. Tomilin

Mordovian State University

Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005

M. Pryanichnikova

Mordovian State University

Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005

Yu. Tsebulaeva

Mordovian State University

Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005

O. Boyarkina

Mordovian State University

Autor responsável pela correspondência
Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005

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