Reaction of 1,5-diphenyl-3-arylverdazyles with СН-acids
- Autores: Tanaseichuk B.S.1, Tomilin O.B.1, Pryanichnikova M.K.1, Tsebulaeva Y.V.1, Boyarkina O.V.1
-
Afiliações:
- Mordovian State University
- Edição: Volume 53, Nº 5 (2017)
- Páginas: 764-768
- Seção: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/216247
- DOI: https://doi.org/10.1134/S1070428017050189
- ID: 216247
Citar
Resumo
The presence of electron-donor substituents in the phenyl ring at the atom С3 of the tetrazinyl ring increases, and of electron-acceptor substituents reduces the reaction rate of 1,5-diphenyl-3-arylverdazyl radicals with СН-acids. The reaction is described with a kinetic equation of the second order with respect to verdazyl, the process rate is determined by the energy of the electron transfer from the SOMO (singly occupied molecular orbital) of the radical to the LUMO of the СН-acid.
Sobre autores
B. Tanaseichuk
Mordovian State University
Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005
O. Tomilin
Mordovian State University
Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005
M. Pryanichnikova
Mordovian State University
Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005
Yu. Tsebulaeva
Mordovian State University
Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005
O. Boyarkina
Mordovian State University
Autor responsável pela correspondência
Email: orgchem2014@yandex.ru
Rússia, Bolshevistskaya ul. 68, Saransk, 430005
Arquivos suplementares
