Reaction of 1,5-diphenyl-3-arylverdazyles with СН-acids
- 作者: Tanaseichuk B.S.1, Tomilin O.B.1, Pryanichnikova M.K.1, Tsebulaeva Y.V.1, Boyarkina O.V.1
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隶属关系:
- Mordovian State University
- 期: 卷 53, 编号 5 (2017)
- 页面: 764-768
- 栏目: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/216247
- DOI: https://doi.org/10.1134/S1070428017050189
- ID: 216247
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详细
The presence of electron-donor substituents in the phenyl ring at the atom С3 of the tetrazinyl ring increases, and of electron-acceptor substituents reduces the reaction rate of 1,5-diphenyl-3-arylverdazyl radicals with СН-acids. The reaction is described with a kinetic equation of the second order with respect to verdazyl, the process rate is determined by the energy of the electron transfer from the SOMO (singly occupied molecular orbital) of the radical to the LUMO of the СН-acid.
作者简介
B. Tanaseichuk
Mordovian State University
Email: orgchem2014@yandex.ru
俄罗斯联邦, Bolshevistskaya ul. 68, Saransk, 430005
O. Tomilin
Mordovian State University
Email: orgchem2014@yandex.ru
俄罗斯联邦, Bolshevistskaya ul. 68, Saransk, 430005
M. Pryanichnikova
Mordovian State University
Email: orgchem2014@yandex.ru
俄罗斯联邦, Bolshevistskaya ul. 68, Saransk, 430005
Yu. Tsebulaeva
Mordovian State University
Email: orgchem2014@yandex.ru
俄罗斯联邦, Bolshevistskaya ul. 68, Saransk, 430005
O. Boyarkina
Mordovian State University
编辑信件的主要联系方式.
Email: orgchem2014@yandex.ru
俄罗斯联邦, Bolshevistskaya ul. 68, Saransk, 430005
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