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Vol 59, No 4 (2017)

Article

Possible mechanism of horizontal overpressure generation of the Khibiny, Lovozero, and Kovdor ore clusters on the Kola Peninsula

Rebetsky Y.L., Sim L.A., Kozyrev A.A.

Abstract

The paper discusses questions related to the generation of increasing crustal horizontal compressive stresses compared to the idea of the standard gravitational state at the elastic stage or even from the prevalence of horizontal compression over vertical stress equal to the lithostatic pressure. We consider a variant of superfluous horizontal compression related to internal lithospheric processes occurrin in the crust of orogens, shields, and plates. The vertical ascending movements caused by these motions at the sole of the crust or the lithosphere pertain to these and the concomitant exogenic processes giving rise to denudation and, in particular, to erosion of the surfaces of forming rises. The residual stresses of the gravitational stressed state at the upper crust of the Kola Peninsula have been estimated for the first time. These calculations are based on the volume of sediments that have been deposited in Arctic seas beginning from the Mesozoic. The data speak to the possible level of residual horizontal compressive stresses up to 90 MPa in near-surface crustal units. This estimate is consistent with the results of in situ measurements that have been carried out at the Mining Institute of the Kola Science Center, Russian Academy of Sciences (RAS), for over 40 years. It is possible to forecast the horizontal stress gradient based on depth using our concept on the genesis of horizontal overpressure, and this forecasting is important for studying the formation of endogenic deposits.

Geology of Ore Deposits. 2017;59(4):265-280
pages 265-280 views

Age and sources of matter for the Kedrovskoe gold deposit, Northern Transbaikal tegion, Republic of Buryatia: Geochronological and isotopic geochemical constraints

Chugaev A.V., Plotinskaya O.Y., Chernyshev I.V., Lebedev V.A., Belogub E.V., Goltsman Y.V., Larionova Y.O., Oleinikova T.I.

Abstract

The paper presents new geochronological and isotopic geochemical data on gold mineralization of the Kedrovskoe deposit. The deposit is located in the northeastern part of the Transbaikal metallogenic province, Russia’s largest. The Early Permian age (273 ± 4 Ma) of mineralization based on the results of Rb–Sr study of metasomatic rocks is correlated with the age of the final phases of Hercynian magmatism in the Baikal–Muya Foldbelt. The Sr, Nd, and Pb isotopic geochemical characteristics of mineralization show that the host rocks are involved in the formation of the latter. It has been established that ore lead was supplied to the hydrothermal system of the deposit mainly from a geochemical reservoir represented by the Neoproterozoic juvenile continental crust of the Baikal–Muya Foldbelt.

Geology of Ore Deposits. 2017;59(4):281-295
pages 281-295 views

Plavica epithermal Au–Ag–Cu deposit in eastern Macedonia: Geology and 3D model of valuable component distribution in ore

Serafimovski T., Volkov A.V., Serafimovski D., Tasev G., Ivanovski I., Murashov K.Y.

Abstract

The Plavica Au–Ag–Cu deposit is related to the large Neogene volcanic center, which complicates the paleocaldera in the central Kratovo–Zletovo ore district of eastern Macedonia. Based on the geology, ore mineralogy, wall-rock alteration, and fluid inclusions, the Plavica deposit has been referred to the epithermal high-sulfidation type. The general 3D model of orebody at this deposit is based on its general geological structure and complex distribution of metal contents. The framework of the 3D model, which has been constructed in the ArcGIS System, comprises 195 exploration boreholes 47295.8 m in total length. The 3D model allows to a better understanding of distribution of mineralization and supplements the geological data on the deposit.

Geology of Ore Deposits. 2017;59(4):296-304
pages 296-304 views

Niobium in hydrothermal systems related to alkali granites: Thermodynamic description of hydroxo and hydroxofluoride complexes

Lukyanova E.V., Akinfiev N.N., Zotov A.V., Rass I.T., Kotova N.P., Korzhinskaya V.S.

Abstract

Available experimental data on the solubility of Nb2O5 and the stability constants for particles of an aqueous solution in the Nb–O–H–F system were processed. As a result, a set of thermodynamic properties for 25°C and 1 bar was obtained, in addition to the equation parameters for the HKF model (Helgeson–Kirkham–Flowers) for hydroxo and hydroxofluoride niobium complexes. F ion is the most important factor governing the concentration of dissolved Nb: neutral hydroxo complex Nb(OH)5(aq) is formed at a low HF concentration, whereas an increase in HF results in an increase in the first Nb(OH)4F(aq) and second Nb(OH)3F2(aq) fluoride complexes. The Nb(OH)5F oxofluoride anion determines oxide solubility in alkali F-bearing fluids. Neutralization of acidic fluoride solution can be the main factor leading to niobium deposition.

Geology of Ore Deposits. 2017;59(4):305-314
pages 305-314 views

Altered rocks of the Onguren carbonatite complex in the Western Tansbaikal Region: Geochemistry and composition of accessory minerals

Savelyeva V.B., Bazarova E.P., Sharygin V.V., Karmanov N.S., Kanakin S.V.

Abstract

The paper discusses the mineralogy and geochemistry of altered rocks associated with calcite and dolomite–ankerite carbonatites of the Onguren dyke–vein complex in the Western Transbaikal Region. The alteration processes in the Early Proterozoic metamorphic complex and synmetamorphic granite hosting carbonatite are areal microclinization and riebeckitization; carbonates, phlogopite, apatite, and aegirine occur in the near-contact zones of the dolomite–ankerite carbonatite veins; and silicification is displayed within separated zones adjacent to the veins. In aluminosilicate rocks, microclinization was accompanied by an increasing content of K, Fe3+, Ti, Nb (up to 460 ppm), Th, Cu, and REE; Na, Ti, Fe3+, Mg, Nb (up to 1500 ppm), Zr (up to 2800 ppm), Ta, Th, Hf, and REE accumulated in the inner zone of the riebeckitization column. High contents of LnCe (up to 11200 ppm), U (23 ppm), Sr (up to 7000 ppm), Li (up to 400 ppm), Zn (up to 600 ppm), and Th (up to 700 ppm) are typical of apatite–phlogopite–riebeckite altered rock; silicified rock contains up to (ppm): 2000 Th, 20 U, 13000 LnCe, and 5000 Ва. Ilmenite and later rutile are the major Nb carriers in alkali altered rocks. These minerals contain up to 2 and 7 wt % Nb2O5, respectively. In addition, ferrocolumbite and aeschynite-(Ce) occur in microcline and riebeckite altered rocks. Fluorapatite containing up to 2.7 wt % (LnCe)2O3, monazite-(Ce), cerite-(Ce), ferriallanite-(Ce), and aeschynite-(Ce) are the REE carriers in riebeckite altered rock. Bastnäsite-(Ce), rhabdophane-group minerals, and xenotime-(Y) are typical of silicified rock. Thorite, monazite-(Ce), and rhabdophane-group minerals are the Th carriers.

Geology of Ore Deposits. 2017;59(4):315-340
pages 315-340 views