


Vol 56, No 6 (2016)
- Year: 2016
- Articles: 25
- URL: https://journal-vniispk.ru/1083-4877/issue/view/15471
Refractories in Heating Units
Designing Refractories for the Tundish of a Continuous Caster
Abstract
The equipment installed in the chambers of a continuous-caster tundish is examined. An improvement made to this equipment is ensuring the efficient formation of flows of metal in the tundish and creating the conditions necessary for improving the quality of the cast metal.



Article
Improving the Lining of Cars Used in Short Tunnel Furnaces
Abstract
An improved design of lining has been developed for the cars of short PG-30 tunnel furnaces, which are used to fire ceramic tooling: crucibles, cores, and molds for casting products made of heat-resistant alloys. The top part of the refractory layer that is installed on the heat-insulating layer consists of two superimposed panels. All of the panels except for the top panel contain interrupted holes (a total of 44 such holes) that are arranged in staggered fashion and open onto the panels’ main surfaces. The top panel contains blind holes (totalling 22). In assembling the refractory layer, the ends of the panels are connected to one another in such a way that the holes their surfaces are coaxial. The top panel is positioned so that the surface without holes faces upward and the holes on the other surface face downward. The box-inserts that hold the ceramic products which are to be fired are placed on the top panel. Such a design of car significantly reduces its weight while also increasing its service life. Durability is improved in particular for high-speed operation of the cars, such as in the firing of foundry molds for casting nickel alloys.



Improving the Efficiency of Screens with a Linear Electromagnetic Motor
Abstract
Results are reported from studies undertaken to improve the efficiency of screens that are equipped with linear electromagnetic motors and undergo low-frequency resonance during service. The article substantiates the indices that were found to characterize the efficiency of the screens and the improvement made in the design of their main component – the vibration exciter. An efficient size was determined for the air gap in the motors.



Boundary Conditions for Designing the Lining of a Glass-Founding Furnace with Innovative Parameters to Improve Technical Efficiency
Abstract
This article presents results obtained from numerical modeling of external heat exchange in an innovative gas-fired glass-founding furnace with an output of 2.92 tons/m2·day). Unit heat consumption in the furnace is 4.187 MJ/kg. Boundary conditions are determined for designing and building a lining for the working space of the furnace. It is established that the average and maximum temperatures are 1512.6 and 1608.4°C for the roof, 1548.3 and 1596.3°C for the longitudinal wall (on the burner side of the furnace), and 1553.2 and 1622.2°C for the end wall (next to the flow). The average temperatures of the surface of the bath in the founding and fining zones are 1404.8 and 1426.6°C, respectively.



Study of Different Types of Carbon Fiber Oxidation Kinetics
Abstract
Results are given for a study of the effect of treatment temperature on oxidation kinetics of carbon fibers of different structure. It is detected that carbon fiber oxidation by oxygen depends on the production process for fiber manufacture, and as a consequence on the nature of its structure, primarily the degree of crystallinity that governs the number of active centers emerging as oxidation initiators. It is established that oxidation of carbon fibers with a relatively low treatment temperature (up to 2000°C) is approximated by an autocatalytic reaction mechanism.



Thermal Shock-Resistant Ceramic Composites Based on Zirconium Dioxide1
Abstract
Changes in structure, phase composition and crystal structure parameters are studied for materials of the ZrO2–MgO system after cyclic thermal shock effects. Features are revealed for formation of ceramic structure and phase condition with implementation of internal stresses connected with a sharp change in temperature. Optimum compositions are established for refractory materials based on ZrO2 answering high specifications for thermal shock resistance and refractoriness.






Study of Sodium Silicate System Firing During Glass Ceramic Foam Preparation
Abstract
The effect of temperature on foaming a mixture of diatomite and sodium hydroxide solution during glass ceramic foam preparation is studied. Composite foaming temperature is established conforming to optimum structural porosity and average specimen density required for heat insulation materials. The effect of temperature on the content within specimens of free sodium hydroxide is analyzed, and its reduction with an increase in temperature is revealed. The practical significance of this research is demonstrated on the example of preparing granular glass ceramic foam.



Quantitative Structural Analysis of Permeable Ceramic Made from Narrow-Fraction Electrocorundum Powder of Different Fineness
Abstract
Permeable ceramic pore structure made from electrocorundum powder grades F 100, F 150, F 240, and F 600 is studied using SEM-image computer analysis in order to obtain such quantitative indices as pore shape, pore shape distribution, pore sinuosity factor, etc. It is shown that ceramic pore shape has a decisive effect on its permeability.



Analysis of the Reliability of Ceramic Parts After Hydroabrasive Machining
Abstract
Arelationship has been experimentally established between the parameters of hydroabrasive machining on the one hand and the morphology of the working surfaces and geometry of VOK71 plates on the other hand. It is determined that hydroabrasive machining significantly improves the reliability of the plates by favorably changing the morphology of their working surfaces and cutting edge and improving the radius of curvature of the cutting edge.



Ceramic Matrix Composites Reinforced with Carbon Nanotubes: Spark Plasma Sintering, Modeling, Optimization
Abstract
The method of spark plasma sintering is used to obtain an α-Al2O3-based nanocomposite reinforced with many-walled carbon nanotubes in amounts up to 50 vol.%. A mathematical model is constructed to describe the change in porosity during the sintering operation. The model accounts for the physico-chemical essence of the processes which take place during spark plasma sintering. Results obtained from experimental studies and mathematical modeling are used to determine the optimum sintering regime, which makes it possible to obtain a composite that has zero porosity and a carbon-nanotube content up to 50 vol.%.






Creation of a Combined Liquid Phenolfomaldehyde Antioxidant-Modifier for Improving Periclase-Carbon Refractory Life
Abstract
Results are given for creation of combined antioxidants for protecting graphite from oxidation based on ethyl silicate, Al, and nickel oxalate, or based on ethyl silicate with addition of nickel sulfate (chloride) and Al. results are given for optimizing the composition for combined antioxidants based on nickel oxalate, Al, and ethyl silicate. The effect of combined antioxidant-modifiers on the properties of periclase-carbon refractory specimens containing 3% graphite is demonstrated.



Research in the Field of Preparing Molded and Unmolded Refractories Based on High-Alumina HCBS. Part 3. Effect of Firing Temperature on Sintering and Mullitization of Materials Prepared on the Basis of Composite Composition HCBS1
Abstract
The effect of firing temperature on sintering and mullitization of six batches of specimens prepared from HCBS based on high-alumina bauxite and very fine quartz glass (VFQG) is studied. In the range 900 – 1200°C (soaking 1 h) normal sintering is noted accompanied by insignificant (0.4 – 0.5%) shrinkage and a sharp increase in ultimate strength in bending (110 – 130 MPa). In the range 1200 – 1400 of 1500°C (depending on composition) specimen growth by 1.0 – 2.5% is noted, due to mullitization. Depending on composition and solid phase fineness the start of sintering for mullitized specimens is noted at temperatures exceeding 1400 – 1500°C. Specimen material modeling a matrix system of high-alumina refractories has high strength and volume constancy after prolonged thermal ageing.



Beryllium Oxide Powder Microstructure During Production Processing
Abstract
Beryllium carbonate and hydroxide powders are studied during production processing in order to prepare pure BeO powder. Powders are supplied by the Ul’binsk Metallurgical Plant (Kazakhstan Republic). It is established that beryllium oxide powder crystallinity and morphology depend to a considerable extent on production treatment type and regimes. Microphotographs of different powder batches point to a genetic connection of their morphology with type of starting raw material, which in turn may have a marked effect on slip and press-mix preparation, on molding, and also on sintering of ceramic objects and their properties.



Coal Tar Pitch Modification Methods: Effect of Surfactant Substances and Carbon Additives on Binder Properties
Abstract
The effect of modifying coal tar pitch with different additives is studied; surfactant substances (SAS), carbon-containing modifiers, and high-temperature binder additives. Using SAS a reduction is observed in viscosity for a system of original pitch–modifier, and with a concentration of 7 wt.% it is most effective to use oleic acid, but with a concentration of 10 wt.% to use myristic acid. In both cases viscosity is reduced by almost a factor of ten with respect to original pitch viscosity. In the case of carbon-containing additives viscosity increases, the same as with use of a high-temperature binder. The effect of modifiers on coke residue yield is studied. On modifying pitch with SAS the reduction in coke residue obeys an additivity rule, which is explained by total removal of SAS from a pitch–modifier system. With use of carbon-containing modifiers and high-temperature binder the coke residue also increases by an additive rule.



Study of the Sintering Mechanism of a Material Obtained from Crystallized Castings Prepared from Discharges of Lithium-Aluminosilicate Glass After Casting
Abstract
Studies are made of the sintering mechanism of a material produced from castings crystallized at 850°C for 2 h. The cast products are obtained from discharges of lithium-aluminosilicate glass after its casting. The apparent activation energies for sintering materials OTM-357, 357-C, and OTM-357-O were calculated and were determined to be 65 ± 15, 155 ± 15, and 245 ± 15 kcal/mole, respectively.



Numerical Modeling of the Stress-Strained State of a Surface Layer of Oxide-Carbide Ceramic with Jet-Abrasive Treatment
Abstract
The stress-strained state of a surface layer of oxide-carbide ceramic under action of a concentrated force, heat flow, and combined loading is studied. The possibility is demonstrated of using the correlation revealed for predicting the nature of ceramic surface breakdown with jet-abrasive treatment.



Review of RF Patents for Refractory Inventions



Raw Materials
Study of the Structure and Properties of Graphites for Refractory Production. Part 1. Physicochemical Study of Graphites from Different Deposits
Abstract
Results are provided for a study of the microstructure, phase composition, and physicochemical properties of domestic and imported graphites for the refractory industry. It is established that graphites of different origin have a different morphological surface, crystal lattice structure, and oxidation resistance.



Production and Equipment
Results from Study of a Pneumatic System for Transporting Nanoparticle-Bearing Lime Dust at the Serov Ferroalloys Plant
Abstract
A description is presented of the system used by the Serov Ferroalloys plant for the pneumatic transport of lime dust that contains nanoparticles. The morphology of the particles of well-burnt lime is discussed. Recommendations are given on ensuring stable operation of the system and subjecting the dust to additional comminution.



Heat Engineering
Developing an Energy-Efficient Lining for the Firing Zone of a High-Temperature Tunnel Furnace
Abstract
Boundary conditions and a method of calculation are examined for determining parameters that characterize heat transfer through the lining of a tunnel furnace. An energy-efficient structure is conceived for the linings of the roof and walls of the furnace and the floor of the cars used in the furnace. It is established that the improvements made in the structure of the furnace’s protective elements make the production process more energy-efficient and create the conditions necessary for also improving the quality of heat treatment of the raw materials/semifinished products. The author determines the amount heat loss and the temperature of the outside surface of the lining for which the temperature gradients from the tunnel axis to the furnace walls and roof and the car floor are no greater than 17, 25, and 43°C, respectively.



Scientific Research and Development
Preparation of Highly Concentrated Binder Suspensions Based on Magnesium Aluminum Silicate Glass
Abstract
Wet milling in a ball mill is used to prepare a suspension based on amorphous and crystallized magnesium aluminum silicate glass. The stabilizing additives used are hydrochloric and oxalic acids, and also an aqueous ammonia solution. Raw material is molded by slip casting in porous molds. Optimum ranges are provided for magnesium aluminum silicate glass suspension casting parameters in order to prepare green workpieces with not more than 30% porosity.



Ecology
Modeling of Air and Dust Flows in the Range of Action of a Round Suction Funnel Above an Impermeable Plane. Part 1. A Mathematical Model and Algorithm for its Computer Implementation
Abstract
A mathematical model and computer program for use in calculating the separation region at the inlet to a funnel situated above an impermeable plane are developed by means of stationary discrete vortex rings. The basic computational relationships and algorithms for calculating the characteristic regions of detached flow, the limiting trajectories of dust particles, and the ventilation region are presented.



Inventions
Review of RF Patents for Refractory Inventions


