


Volume 57, Nº 3 (2016)
- Ano: 2016
- Artigos: 25
- URL: https://journal-vniispk.ru/1083-4877/issue/view/15497
Refractories in Heating Units
Analysis of Operation of a Steel-Pouring Ladle–Tundish System for a Section CBCM and Improved Refractory Structures of the Tundish Receiving Chamber
Resumo
Operation of a section CBCM steel-pouring ladle–tundish, and also questions of organizing steel flow movement in the tundish receiving chamber are analyzed. The considerable effect of new components of refractory structures on metal flow parameters in the tundish receiving chamber is demonstrated. Contemporary equipment of the receiving chamber provides effective formation of metal flow in the chamber and trouble-free CBCM operation.



Article



Study of an Electric Furnace Physical Model for Firing Vermiculite with a “Zero” Module
Resumo
Results are considered for experimental research carried out in a test furnace for checking the possibility of completing heat assimilation by vermiculite grains and structure formation within them due to transfer of vermiculite exergy into mechanical transformation energy in a so-called “zero” module with reduced energy requirement. A relationship is established by experiment for vermiculite product density at the inlet to the “zero” module and at the outlet from it on temperature of the heater surfaces in the furnace electric modules. Time is determined for passage of a vermiculite grain through the “zero” module, and a value of complete heat assimilation factor is established correcting the analytical model of the process. An analytical expression is provided describing vermiculite heat assimilation taking account of the correcting completeness factor. It is shown that use of a “zero” module may reduce the energy requirement and firing power requirement by 10 – 20% in relation to “zero” module installation location.



Mullite-Corundum Material Based on High-Alumina Chamotte Grade RASC
Resumo
A simplex-lattice method is used for planning an experiment for sorting the grain size composition of high-alumina chamotte grade RASC in order to prepare mullite material. Optimum chamotte grain size composition is established proving an improvement in operating properties.



Complex Clinker-Less Binder Made from Refractory Wastes and Products Based on it. Part 3. Optimization of Complex Binder Composition Based on Cake and Grinding Powder and Establishment of a Correlation Between Production Factors and its Properties1
Resumo
A four-factor experiment is planned and carried out in order to establish the effect of each complex binder component and its preparation temperature. Input, output parameters and stable factors, the level of variation of independent variables, the correlation of production factors with physicomechanical properties of binder stone in a water-saturated condition and after drying, are determined.






Influence of Microstructure on Formation of Deterioration Layer in Periclase-Hercynite Bricks
Resumo
The microstructure of the original layer and the cement melt-penetrated layer of a used periclase-hercynite brick from a cement rotary kiln with a daily output of 5000 tons for 12 months was studied by XRD, SEM, EDS, and a mercury porosimeter. The results show that the cation diffusion between hercynite and periclase particles in the brick at high temperatures decreases the pore size of the brick. The pore size in the original layer is located mainly in the range of 4 – 20 μm; the decreased pore size increases the penetration resistance of the cement melt to the inside of the brick and makes the cement melt react with the pore walls better. The components of the matrix pore walls such as MgO and Al2O3 dissolve in the cement melt, enhancing the hot properties of the penetrated melt, decreasing the penetration depth, and slowing the formation of the deterioration layer. The pore structure and the element distribution endow the brick with good thermal shock resistance.



Periclase-Carbon Refractory Properties with a Different Amount of Graphite in the Charge Using Liquid PFR and Graphite as Modifiers
Resumo
are given for a study of the effect of introducing different amounts of graphite modified PFR and graphite into a periclase-carbon (PC) refractory charge based on fuzed periclase. The PFR modifier used is ÉTS-40, and the graphite modifier is a sol based on ÉTS-40 hydrolysate and 20% NiCl2 solution. A production scheme is proposed for preparing PC-refractories with combined modification of components, and also a charge composition with 15 – 20% graphite demonstrating sufficiently good slag resistance.



UHF-Energy Absorbents Based on Products of Aluminum-Magnesium Alloy Chemical Dispersion Products
Resumo
Results are given for studying electrophysical properties of ceramic materials based on powders prepared by chemical dispersion of aluminum-magnesium alloys. The possibility is demonstrated of using these materials as UHF-energy bulk absorbents. It is shown that good test material thermal stability makes it possible to use it as heat insulation and refractory material in systems requiring protection from UHF-energy.



Micromachining of a High-Density Current-Conducting Ceramic with the Use of Electrical-Discharge Machining. Part 2
Resumo
Production features of micromachining ceramic workpieces using electrical-discharge machining are studied. The effect of pulse duration, breakdown voltage, voltage gain factor, peak current strength, and working voltage for electrical-discharge machining of VOK71 ceramic workpieces on roughness at the bottom of a channel and electrode-tool end wear are established. A mechanism is proposed for surface formation with electrical-discharge machining of current-conducting ceramic and recommendations are formulated for improving micromachining efficiency for components of this material.






Carbide Formation at a Carbon-Graphite Lining Cathode Surface Wettable with Aluminum
Resumo
For protecting a cathode block surface and a whole electrolyzer lining it is proposed to use boron and titanium compounds in the form of an active substrate of their carbides (TiC and B4C) that under successive electrodeposition conditions with transformation and reaction transitions create a layer wettable with aluminum. Combined synthesis processes are studied for wettable coatings and the mechanism of carbide formation on carbon cathode surface layers. Possible processes of aluminum carbide formation with its transition into carboxide surface substances are suggested for discussion.



Research in the Field of Preparing Molded and Unmolded Refractories Based on High-Alumina HCBS. Part 6. Mullitization and Thermal Expansion of Materials Based on Compound Composition HCBS1
Resumo
Sintering and mullitization are studied for specimens prepared on the basis of compound composition HCBS in the system bauxite – very fine quartz glass (VFQG), and also with addition of refractory clay. The nature of sintering and mullitization is governed to a considerable extent by SiO2 content in the original composition (VFQG + clay). Dilatometric studies of specimens previously fired at 1600°C established that depending on composition thermal expansion values in the range 20 – 1000°C are within the limits of 0.5 – 0.6%, which is close or comparable with similar data for pure mullite.



Kinetics of Fuzed Periclase Wetting with Coal-Tar Pitch
Resumo
Results are given for a study of the mechanism of periclase wetting by coal-tar pitch. Features are revealed for pitch reaction with a periclase surface caused by differences in pitch chemical composition and conversion of components during thermal action.



Stressed State of a Boundary Between Ceramic and Coating Under Action of a Combined Load
Resumo
Basic features are revealed for the stressed state of a boundary between ceramic and coating with simultaneous action of heat flow, and concentrated and distributed forces. The effect of ceramic grain material on the stressed state of a ceramic–coating boundary is determined.



Quantitative Analysis of Permeable Ceramic Structure Made From Narrow-Fraction Electrocorundum Powder and Corundum Hollow Microspheres
Resumo
The structure of permeable ceramic made from narrow-fraction electrocorundum grade F 240 and corundum hollow microspheres is studied using computer analysis of images obtained in a scanning electron microscope. Such quantitative indices are determined as pore shape, pore shape distribution, pore twisting factor, etc. It is shown that pore shape has a decisive effect on specimen permeability.



Physicochemical Study of Alumochromium-Containing Refractories Developed by Self-Propagating High-Temperature Synthesis
Resumo
Results are given for a study of the main physicochemical properties of a new alumochromium-containing refractory composition developed by self-propagating high-temperature synthesis. The basis of the chemically stable refractory materials obtained is production waste, i.e., ferrochrome slag, and chromite concentrate. The good chemical stability, refractoriness, mechanical strength, hardness, and wear resistance govern the possibility of use in preparing corrosion-resistant, refractory objects, plasters, and concretes.



Interaction of Copper Oxide with Zirconium Dioxide Stabilized with Yttrium Oxide
Resumo
The effect of adding copper oxide in an amount of 0.9 wt.% on sintering capacity, microstructure, and phase composition of material based on zirconium dioxide stabilized with yttrium oxide is studied. Powder is prepared by reverse precipitation with ammonia from aqueous solutions. It is shown that in the presence of copper oxide there is formation of monoclinic zirconium dioxide, appearance of a liquid phase in the range 1120 – 1200°C, and a change in material color and porosity.



Raw Materials
Satkinsk Deposit Magnesite Enrichment by an X-Ray Transmission Method
Resumo
Industrial test approval is carried out in AO Magnezit Combine for Satkinsk magnesite separation technology using an x-ray transmission separator XSS(T). Favorable results are obtained with a “dry” enrichment method of x-ray transmission separation. A procedure is worked out for enriching magnesia raw material of different quality using magnesite (SiO2 content not more than 1.1%; CaO not more than 2.1%) corresponding to specifications for producing standard grades of basic composition objects.



Production and Equipment
Dust Formation and a Solution for Dust Collection During Economic Mineral Processing in Quarries
Resumo
Dust formation in refractory production quarries and its danger for the health of service personnel are studied. Dust properties are provided in relation to particle size. Well-known methods are considered for collection of harmful dust and disadvantages are considered. A new means of transport is considered for high throughput using an air cushion for collection and transport of dust-forming loose materials under conditions impassable by land.



Heat Engineering
Transformation of Vermiculite Energy Into Mechanical Transformation Energy During Firing in Electric Furnaces With a “Zero” Module
Resumo
Models are considered for vermiculite heat assimilation and thermal conductivity during heating in electric furnaces with a “zero” module using the internal thermal exergy for mechanical transformation of its grains without an external heat source. Models are analyzed taking account of vermiculite fine fraction and inert material stored energy, and evaluation of their effect on heat assimilation and structure formation of coarser fractions.



Scientific Research and Development
Research in the Area of Preparing Materials Based on Fuzed Quartz HCBS. Part 10. Some Properties of Cristobalite-Containing Materials1
Resumo
The effect of repeated nonisothermal heating to 1500°C on shrinkage and crystallization of quartz ceramic with added alkali (0.5% Na2O) and monolithic fuzed quartz is studied. Marked (up to 10%) tridymite formation is detected in specimens with added alkali and with a predominant cristobalite content. Some properties are provide for specimens after single-stage heating to 1500°C. Depending on additive content specimens have open porosity of 6 – 9% and ultimate strength in compression of 130 – 185 MPa.



Ecology
Modeling Dust and Air Flow Within an Aspirated Shelter
Resumo
Within the scope of a model for a viscous compressible liquid spatial dust and air flow in an aspirated shelter fitted with a rotary suction cylinder is studied. Structural and regime parameters are determined for a rotary suction cylinder effectively influencing a reduction in dust entrainment in an aspiration circuit.



Quality and Certification
Study of Heat Insulation Material Thermal Conductivity by a Hot-Wire Method
Resumo
The possibility is considered of using a hot-wire method (cross-array method) for determining heat insulation material thermal conductivity at high temperature. These tests show that different indices obtained by the hot-wire method and the steady-state standard do not exceed 12 – 15%.



Erratum
Erratum to: Ceramic of the Mullite–ZrO2–SiAlON System During Spark Plasma Sintering


