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Volume 57, Nº 3 (2016)

Refractories in Heating Units

Analysis of Operation of a Steel-Pouring Ladle–Tundish System for a Section CBCM and Improved Refractory Structures of the Tundish Receiving Chamber

Vdovin K., Tochilkin V., Tochilkin V.

Resumo

Operation of a section CBCM steel-pouring ladle–tundish, and also questions of organizing steel flow movement in the tundish receiving chamber are analyzed. The considerable effect of new components of refractory structures on metal flow parameters in the tundish receiving chamber is demonstrated. Contemporary equipment of the receiving chamber provides effective formation of metal flow in the chamber and trouble-free CBCM operation.

Refractories and Industrial Ceramics. 2016;57(3):221-223
pages 221-223 views

Article

Experience of Using Monoblock Stoppers with a Magnesia Head Section1

Korostelev A., S’emshchikov N., Chernyshev A., Semin A., Bel’maz K., Bozheskov A., Kazakov V., Kosonogov A.

Resumo

Monoblock stoppers of different quality in metallurgical enterprises are analyzed and the effect of stopper material on metal pouring stability in a CBCM is demonstrated.

Refractories and Industrial Ceramics. 2016;57(3):224-228
pages 224-228 views

Study of an Electric Furnace Physical Model for Firing Vermiculite with a “Zero” Module

Nizhegorodov A., Zvezdin A.

Resumo

Results are considered for experimental research carried out in a test furnace for checking the possibility of completing heat assimilation by vermiculite grains and structure formation within them due to transfer of vermiculite exergy into mechanical transformation energy in a so-called “zero” module with reduced energy requirement. A relationship is established by experiment for vermiculite product density at the inlet to the “zero” module and at the outlet from it on temperature of the heater surfaces in the furnace electric modules. Time is determined for passage of a vermiculite grain through the “zero” module, and a value of complete heat assimilation factor is established correcting the analytical model of the process. An analytical expression is provided describing vermiculite heat assimilation taking account of the correcting completeness factor. It is shown that use of a “zero” module may reduce the energy requirement and firing power requirement by 10 – 20% in relation to “zero” module installation location.

Refractories and Industrial Ceramics. 2016;57(3):246-251
pages 246-251 views

Mullite-Corundum Material Based on High-Alumina Chamotte Grade RASC

Kashcheev I., Bayandina M., Bayandina T.

Resumo

A simplex-lattice method is used for planning an experiment for sorting the grain size composition of high-alumina chamotte grade RASC in order to prepare mullite material. Optimum chamotte grain size composition is established proving an improvement in operating properties.

Refractories and Industrial Ceramics. 2016;57(3):258-261
pages 258-261 views

Complex Clinker-Less Binder Made from Refractory Wastes and Products Based on it. Part 3. Optimization of Complex Binder Composition Based on Cake and Grinding Powder and Establishment of a Correlation Between Production Factors and its Properties1

Sokov V., Sokov V.

Resumo

A four-factor experiment is planned and carried out in order to establish the effect of each complex binder component and its preparation temperature. Input, output parameters and stable factors, the level of variation of independent variables, the correlation of production factors with physicomechanical properties of binder stone in a water-saturated condition and after drying, are determined.

Refractories and Industrial Ceramics. 2016;57(3):262-263
pages 262-263 views

Complex Clinker-Less Binder Made From Refractory Wastes and Products Based on it. Part 4. Study of CLCP-Powder Stone Structure1

Sokov V., Sokov V.

Resumo

The structure of hardened CLCP-stone is studied using petrographic, x-ray structural, differential-thermal, chemical, and electron microscope methods.

Refractories and Industrial Ceramics. 2016;57(3):264-266
pages 264-266 views

Influence of Microstructure on Formation of Deterioration Layer in Periclase-Hercynite Bricks

Chen J., Liu D., Yan M., Jiang P., Li B., Sun J.

Resumo

The microstructure of the original layer and the cement melt-penetrated layer of a used periclase-hercynite brick from a cement rotary kiln with a daily output of 5000 tons for 12 months was studied by XRD, SEM, EDS, and a mercury porosimeter. The results show that the cation diffusion between hercynite and periclase particles in the brick at high temperatures decreases the pore size of the brick. The pore size in the original layer is located mainly in the range of 4 – 20 μm; the decreased pore size increases the penetration resistance of the cement melt to the inside of the brick and makes the cement melt react with the pore walls better. The components of the matrix pore walls such as MgO and Al2O3 dissolve in the cement melt, enhancing the hot properties of the penetrated melt, decreasing the penetration depth, and slowing the formation of the deterioration layer. The pore structure and the element distribution endow the brick with good thermal shock resistance.

Refractories and Industrial Ceramics. 2016;57(3):267-272
pages 267-272 views

Periclase-Carbon Refractory Properties with a Different Amount of Graphite in the Charge Using Liquid PFR and Graphite as Modifiers

Semchenko G., Povshuk V., Starolat E., Borisenko O.

Resumo

Results

are given for a study of the effect of introducing different amounts of graphite modified PFR and graphite into a periclase-carbon (PC) refractory charge based on fuzed periclase. The PFR modifier used is ÉTS-40, and the graphite modifier is a sol based on ÉTS-40 hydrolysate and 20% NiCl2 solution. A production scheme is proposed for preparing PC-refractories with combined modification of components, and also a charge composition with 15 – 20% graphite demonstrating sufficiently good slag resistance.

Refractories and Industrial Ceramics. 2016;57(3):273-278
pages 273-278 views

UHF-Energy Absorbents Based on Products of Aluminum-Magnesium Alloy Chemical Dispersion Products

Ponomarev S., Tarasovskii V., Koshkin V., Borovin Y.

Resumo

Results are given for studying electrophysical properties of ceramic materials based on powders prepared by chemical dispersion of aluminum-magnesium alloys. The possibility is demonstrated of using these materials as UHF-energy bulk absorbents. It is shown that good test material thermal stability makes it possible to use it as heat insulation and refractory material in systems requiring protection from UHF-energy.

Refractories and Industrial Ceramics. 2016;57(3):279-282
pages 279-282 views

Micromachining of a High-Density Current-Conducting Ceramic with the Use of Electrical-Discharge Machining. Part 2

Kuzin V., Fedorov S., Szalay T., Farkas B.

Resumo

Production features of micromachining ceramic workpieces using electrical-discharge machining are studied. The effect of pulse duration, breakdown voltage, voltage gain factor, peak current strength, and working voltage for electrical-discharge machining of VOK71 ceramic workpieces on roughness at the bottom of a channel and electrode-tool end wear are established. A mechanism is proposed for surface formation with electrical-discharge machining of current-conducting ceramic and recommendations are formulated for improving micromachining efficiency for components of this material.

Refractories and Industrial Ceramics. 2016;57(3):283-287
pages 283-287 views

Reinforcement of Periclase-Carbon Refractories with Carbon Fibers1

Kashcheev I., Zemlyanoi K., Pomortsev S., Valuev A., Borisova Y.

Resumo

The possibility is considered of using carbon fibers as a reinforcing element within the structure of periclase-carbon refractories. Laboratory and industrial test results are provided.

Refractories and Industrial Ceramics. 2016;57(3):288-291
pages 288-291 views

Carbide Formation at a Carbon-Graphite Lining Cathode Surface Wettable with Aluminum

Gorlanov E., Bazhin V., Fedorov S.

Resumo

For protecting a cathode block surface and a whole electrolyzer lining it is proposed to use boron and titanium compounds in the form of an active substrate of their carbides (TiC and B4C) that under successive electrodeposition conditions with transformation and reaction transitions create a layer wettable with aluminum. Combined synthesis processes are studied for wettable coatings and the mechanism of carbide formation on carbon cathode surface layers. Possible processes of aluminum carbide formation with its transition into carboxide surface substances are suggested for discussion.

Refractories and Industrial Ceramics. 2016;57(3):292-296
pages 292-296 views

Research in the Field of Preparing Molded and Unmolded Refractories Based on High-Alumina HCBS. Part 6. Mullitization and Thermal Expansion of Materials Based on Compound Composition HCBS1

Pivinskii Y., Dyakin P., Kolobov A.

Resumo

Sintering and mullitization are studied for specimens prepared on the basis of compound composition HCBS in the system bauxite – very fine quartz glass (VFQG), and also with addition of refractory clay. The nature of sintering and mullitization is governed to a considerable extent by SiO2 content in the original composition (VFQG + clay). Dilatometric studies of specimens previously fired at 1600°C established that depending on composition thermal expansion values in the range 20 – 1000°C are within the limits of 0.5 – 0.6%, which is close or comparable with similar data for pure mullite.

Refractories and Industrial Ceramics. 2016;57(3):297-303
pages 297-303 views

Kinetics of Fuzed Periclase Wetting with Coal-Tar Pitch

Lysova G., Borovik S.

Resumo

Results are given for a study of the mechanism of periclase wetting by coal-tar pitch. Features are revealed for pitch reaction with a periclase surface caused by differences in pitch chemical composition and conversion of components during thermal action.

Refractories and Industrial Ceramics. 2016;57(3):304-307
pages 304-307 views

Stressed State of a Boundary Between Ceramic and Coating Under Action of a Combined Load

Kuzin V., Fedorov M.

Resumo

Basic features are revealed for the stressed state of a boundary between ceramic and coating with simultaneous action of heat flow, and concentrated and distributed forces. The effect of ceramic grain material on the stressed state of a ceramic–coating boundary is determined.

Refractories and Industrial Ceramics. 2016;57(3):308-312
pages 308-312 views

Quantitative Analysis of Permeable Ceramic Structure Made From Narrow-Fraction Electrocorundum Powder and Corundum Hollow Microspheres

Tarasovskii V., Krasnyi B., Koshkin V., Borovin Y., Vasin A., Smirnov A., Kudryash M.

Resumo

The structure of permeable ceramic made from narrow-fraction electrocorundum grade F 240 and corundum hollow microspheres is studied using computer analysis of images obtained in a scanning electron microscope. Such quantitative indices are determined as pore shape, pore shape distribution, pore twisting factor, etc. It is shown that pore shape has a decisive effect on specimen permeability.

Refractories and Industrial Ceramics. 2016;57(3):313-316
pages 313-316 views

Physicochemical Study of Alumochromium-Containing Refractories Developed by Self-Propagating High-Temperature Synthesis

Satbaev S., Satbaev B., Koketaev A., Aimbetova É., Shalabaev N.

Resumo

Results are given for a study of the main physicochemical properties of a new alumochromium-containing refractory composition developed by self-propagating high-temperature synthesis. The basis of the chemically stable refractory materials obtained is production waste, i.e., ferrochrome slag, and chromite concentrate. The good chemical stability, refractoriness, mechanical strength, hardness, and wear resistance govern the possibility of use in preparing corrosion-resistant, refractory objects, plasters, and concretes.

Refractories and Industrial Ceramics. 2016;57(3):317-320
pages 317-320 views

Interaction of Copper Oxide with Zirconium Dioxide Stabilized with Yttrium Oxide

Porozova S., Sirotenko L., Shokov V., Gurov A.

Resumo

The effect of adding copper oxide in an amount of 0.9 wt.% on sintering capacity, microstructure, and phase composition of material based on zirconium dioxide stabilized with yttrium oxide is studied. Powder is prepared by reverse precipitation with ammonia from aqueous solutions. It is shown that in the presence of copper oxide there is formation of monoclinic zirconium dioxide, appearance of a liquid phase in the range 1120 – 1200°C, and a change in material color and porosity.

Refractories and Industrial Ceramics. 2016;57(3):321-324
pages 321-324 views

Raw Materials

Satkinsk Deposit Magnesite Enrichment by an X-Ray Transmission Method

Aksel’rod L., Turchin M., Nazmiev M., Manuilova E., Galikhanov I.

Resumo

Industrial test approval is carried out in AO Magnezit Combine for Satkinsk magnesite separation technology using an x-ray transmission separator XSS(T). Favorable results are obtained with a “dry” enrichment method of x-ray transmission separation. A procedure is worked out for enriching magnesia raw material of different quality using magnesite (SiO2 content not more than 1.1%; CaO not more than 2.1%) corresponding to specifications for producing standard grades of basic composition objects.

Refractories and Industrial Ceramics. 2016;57(3):229-233
pages 229-233 views

Production and Equipment

Dust Formation and a Solution for Dust Collection During Economic Mineral Processing in Quarries

Davydov S., Belov S., Cheremisina T.

Resumo

Dust formation in refractory production quarries and its danger for the health of service personnel are studied. Dust properties are provided in relation to particle size. Well-known methods are considered for collection of harmful dust and disadvantages are considered. A new means of transport is considered for high throughput using an air cushion for collection and transport of dust-forming loose materials under conditions impassable by land.

Refractories and Industrial Ceramics. 2016;57(3):234-238
pages 234-238 views

Heat Engineering

Transformation of Vermiculite Energy Into Mechanical Transformation Energy During Firing in Electric Furnaces With a “Zero” Module

Nizhegorodov A., Zvezdin A.

Resumo

Models are considered for vermiculite heat assimilation and thermal conductivity during heating in electric furnaces with a “zero” module using the internal thermal exergy for mechanical transformation of its grains without an external heat source. Models are analyzed taking account of vermiculite fine fraction and inert material stored energy, and evaluation of their effect on heat assimilation and structure formation of coarser fractions.

Refractories and Industrial Ceramics. 2016;57(3):239-245
pages 239-245 views

Scientific Research and Development

Research in the Area of Preparing Materials Based on Fuzed Quartz HCBS. Part 10. Some Properties of Cristobalite-Containing Materials1

Pivinskii Y., Dyakin P., Kolobov A.

Resumo

The effect of repeated nonisothermal heating to 1500°C on shrinkage and crystallization of quartz ceramic with added alkali (0.5% Na2O) and monolithic fuzed quartz is studied. Marked (up to 10%) tridymite formation is detected in specimens with added alkali and with a predominant cristobalite content. Some properties are provide for specimens after single-stage heating to 1500°C. Depending on additive content specimens have open porosity of 6 – 9% and ultimate strength in compression of 130 – 185 MPa.

Refractories and Industrial Ceramics. 2016;57(3):252-257
pages 252-257 views

Ecology

Modeling Dust and Air Flow Within an Aspirated Shelter

Gol’tsov A., Logachev K., Averkova O.

Resumo

Within the scope of a model for a viscous compressible liquid spatial dust and air flow in an aspirated shelter fitted with a rotary suction cylinder is studied. Structural and regime parameters are determined for a rotary suction cylinder effectively influencing a reduction in dust entrainment in an aspiration circuit.

Refractories and Industrial Ceramics. 2016;57(3):325-331
pages 325-331 views

Quality and Certification

Study of Heat Insulation Material Thermal Conductivity by a Hot-Wire Method

Vartanyan M., Gerasimov R., Pyren’kin O., Dolbilova I., Oistrakh A., Somov A.

Resumo

The possibility is considered of using a hot-wire method (cross-array method) for determining heat insulation material thermal conductivity at high temperature. These tests show that different indices obtained by the hot-wire method and the steady-state standard do not exceed 12 – 15%.

Refractories and Industrial Ceramics. 2016;57(3):332-333
pages 332-333 views

Erratum

Erratum to: Ceramic of the Mullite–ZrO2–SiAlON System During Spark Plasma Sintering

Sedmale G., Rundans M., Sperberga I., Setina J., Cimmers A.
Refractories and Industrial Ceramics. 2016;57(3):334-334
pages 334-334 views