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Vol 25, No 3 (2017)

Laser Formation and Diagnostics of Nanocomposite Materials

Optical properties of nanocomposites based on polymers and metal nanoparticles

Barmina E.V., Mel’nik N.N., Rakov I.I., Shafeev G.A.

Abstract

The optical properties of nanocomposites of metal nanoparticles and polymers of two types have been studied. Gold and silver nanoparticles were obtained by laser ablation of corresponding metal targets in acetone and chloroform. The thus formed colloidal solutions were used to prepare nanocomposites of these nanoparticles in polymer matrices of polymethylmethacrylate (PMMA) and fluorine-containing polymer LF-32. The polymer matrix is found to promote aggregation of the metal nanoparticles under study into elongated chains. In turn, metal nanoparticles affect the polymer matrix. In the case of PMMA, suppression of the vibrational peaks of polymer in the low-frequency region of its Raman spectrum occurs. In the case of LF-32, gold and silver nanoparticles amplify the Raman signal of the polymer matrix. In addition, the Raman spectra of nanocomposites indicate aggregation of disordered carbon around the nanoparticles obtained by laser ablation in organic solvents. The possibilities of studying the ultrafast (about 1 ps) optical response of the nanocomposites obtained in order to use it in photonics elements are discussed.

Physics of Wave Phenomena. 2017;25(3):165-169
pages 165-169 views

Spectroscopy of Photonic Crystals

Coupled optical Tamm states at edges of a photonic crystal enclosed by a composite of core-shell nanoparticles

Vetrov S.Y., Pankin P.S., Timofeev I.V.

Abstract

Coupled optical Tamm states localized at the edges of a photonic crystal enclosed with a nanocomposite are theoretically studied. The nanocomposite consists of nanoparticles with a dielectric core and a metal shell, which are dispersed in a transparent matrix. It is shown that the positions of the spectral peaks are sensitive to the thickness of the outermost photonic crystal layer.

Physics of Wave Phenomena. 2017;25(3):170-174
pages 170-174 views

Reflection spectra of 1D photonic crystals based on aluminum oxide

Gorelik V.S., Yashin M.M., Vodchits A.I.

Abstract

Optical properties (transmission and reflection) of 1D photonic crystals (PCs) based on mesoporous anodic aluminum oxide with the lattice periods of 188 and 194nm are investigated. The experimentally measured reflection spectrum is compared in its first bandgap region with the theoretical dependence obtained from the dispersion relation for the 1D PC. Angular dependence is established for spectral positions of bandgaps in the 1D PC. A possibility of using mesoporous aluminum-oxide-based 1D PCs as narrow-band filters, narrow-band mirrors, and refractive sensors of molecular compounds is analyzed.

Physics of Wave Phenomena. 2017;25(3):175-179
pages 175-179 views

Nonlinear and Parametric Optics

Effect of polarization deviation of spontaneous parametric down-conversion on the degree of biphoton entanglement

Frolovtsev D.N., Magnitskiy S.A.

Abstract

Analysis is given to the effect of polarization deviation due to spontaneous parametric downconversion on the states of polarization-entangled photons generated via a cascaded two-crystal geometry with type I phase matching (e−oo).

Physics of Wave Phenomena. 2017;25(3):180-184
pages 180-184 views

Optical Spectroscopy of Biological Objects

Spectral differences between monomers and trimers of photosystem I depend on the interaction between peripheral chlorophylls of neighboring monomers in trimer

Pishchalnikov R.Y., Shubin V.V., Razjivin A.P.

Abstract

The spatial position of the long-wavelength chlorophylls in trimer of pigment-protein complex of photosystem I (PSI) have been determined bymodeling the optical fluorescence absorption and emission spectra for two hypothetical models of PSI trimer. The calculation has been performed using X-ray diffraction data on the spatial position of chlorophylls in PSI monomer; the pigment site energies were taken from the studies of other researchers, while interactions between monomers in trimer are considered as fitting parameters. The interaction energy between the chlorophylls spaced by a distance smaller than 10 Å was estimated based on the concept of extended dipole−dipole interaction. The model under study allowed us to evaluate the influence of the exciton interaction between peripheral pigments on the optical response of PSI trimer. The intensity and shape of stationary fluorescence line turned out to be sensitive to the PSI monomer packing in trimer. A visualization of the density matrix for low-energy exciton states has made it possible to estimate the localization of long-wavelength chlorophylls in PSI trimer.

Physics of Wave Phenomena. 2017;25(3):185-195
pages 185-195 views

Oscillations of the redox state of the nicotinamide adenine dinucleotide coenzime in an aqueous medium and in microemulsions upon interaction with an endogenous source of nitrogen oxide: S-nitrosoglutathione

Belovolova L.V., Glushkov M.V.

Abstract

The nicotinamide adenine dinucleotide (NADH) coenzime, which is involved in redox transformations in all living cells, fluoresces only in the reduced state. The degradation kinetics of its fluorescence in the reaction with the endogenous source of nitrogen oxide, S-nitrosoglutathione (GSNO), can be separated in two main stages: (i) a sharp decrease in intensity and (ii) a relatively slow exponential stage, against the background of which large-amplitude oscillations of signal intensity are observed. The degradation of NADH fluorescence in water-in-oil microemulsions of anionic surfactant based on sodium bis(2-ethylhexyl)sulfosuccinate (Aerosol OT or AOT) occurs much more rapidly than in a homogeneous buffer solution. The relative contribution of the stepwise stage increases under illumination by a nitrogen laser (337 nm) and with the GSNO and water contents in the microemulsion. When there are on average one NADH molecule and one GSNO molecule per microemulsion bubble, the contribution of the stepwise stage ismuch smaller than for the samples with a lowerNADH content. The rate constant of the slow stage of NADH fluorescence degradation decreases under these conditions, whereas the intensity oscillation frequency increases. Large-amplitude oscillations of the NADH fluorescence intensity in microemulsions are more pronounced in the presence of a buffer (1mM HEPES, pH 7.4) than in pure water. The effects observed are assumed to be due to the shifts of local pH of the aqueous microenvironment of reagents in microemulsion bubbles and to the participation of buffer radical cations in the reduction of the intermediate radical NAD• to NADH.

Physics of Wave Phenomena. 2017;25(3):196-206
pages 196-206 views

Light Effect on Biological Objects

Effect of visible light on biological objects: Physiological and pathophysiological aspects

Gudkov S.V., Andreev S.N., Barmina E.V., Bunkin N.F., Kartabaeva B.B., Nesvat A.P., Stepanov E.V., Taranda N.I., Khramov R.N., Glinushkin A.P.

Abstract

Visible light is a necessary condition for the existence of life on the Earth. The food and oxygen consumed by humans, directly or mediately, are products of photosynthesis: conversion of light energy into the energy of chemical bonding in organic matter. Visible light not only provides photosynthesis in plants; it is also involved in the regulation of many reactions (from molecular to behavioral) in the animal world. This review is devoted to the questions concerning the role of light in the life of biological objects and the physical mechanisms of interaction of visible light with matter. The effect of light on the molecular and physiological reactions of a human and its microflora is analyzed. The existing methods and the application potential of light effects in diagnostics and therapy are considered.

Physics of Wave Phenomena. 2017;25(3):207-213
pages 207-213 views

Diode Lasers

Analysis of the radiation pattern of laser diode radiation based on experimental data

Bliznyuk V.V., Berezovskaya N.V., Brit M.A., Koval O.I., Parshin V.A., Rzhanov A.G.

Abstract

It is shown that the radiation pattern of laser diode radiation can quantitatively be analyzed without labor-intensive and expensive measurements of the radiation intensity distribution in the near-field zone. Formulas are obtained in the explicit form, which analytically describe the radiation pattern of laser diode radiation in free space, and a simple algorithm is developed for determining the fundamental lasing mode.

Physics of Wave Phenomena. 2017;25(3):214-218
pages 214-218 views

Laser Diagnostics of Aqueous Solutions

Suppression of the coalescence of gas bubbles in aqueous electrolyte solutions: dependence on the external pressure and velocity of gas flow through a column with liquid

Bunkin N.F., Drozdov A.N., Drozdov N.A., Kozlov V.A., Tuan V.M., Fouilhe V.L.

Abstract

An experiment on laser diagnostics of gas bubbles moving in aqueous solutions of different electrolytes has revealed that efficient suppression of gas bubble coalescence (collapse) occurs at certain concentrations of cation−anion pairs. It is experimentally proven that there is an optimal ion composition at which the coalescence is suppressed in a wide range of velocities of gas particle flow through a column with liquid. It is shown that the threshold ion concentrations corresponding to the onset of coalescence suppression decrease with an increase in the external pressure in the liquid. The results obtained can be used in oil production technologies to solve the problem of burning associated oil gas in torches.

Physics of Wave Phenomena. 2017;25(3):219-224
pages 219-224 views

Remote Sensing of Natural Media

Lidar sensing of ship wakes

Grishin M.Y., Lednev V.N., Pershin S.M., Bunkin A.F., Ermakov S.A., Kapustin I.A., Mol’kov A.A.

Abstract

Detection of ship wakes is utterly important for ship traffic monitoring, security of sea borders, etc. Among standard detection methods there are radar and acoustic sensing, photographing, hyperspectral measurements, and water sample analysis. However, these methods are hardly suitable for detecting wakes of light high-speed boats. An alternative is optical methods, in particular laser remote sensing. In this work, laboratory experiments on laser remote sensing of water perturbed by a propeller rotating at up to 20 000 rpm are described. A long (over 5 h) decrease in the integral of the band of OH stretching vibrations inH2Omolecules in the Raman scattering spectrum and a blueshift of theOHband center by 2.5 to 3 cm−1 are demonstrated.

Physics of Wave Phenomena. 2017;25(3):225-230
pages 225-230 views

Dielectric Spectroscopy of Ferroelectrics

Dielectric losses in the triglycine sulfate crystal under heating and cooling

Ovchinnikova G.I., Eremeev A.P., Belugina N.V., Gainutdinov R.V., Ivanova E.S., Tolstikhina A.L.

Abstract

Temperature dynamics of the dielectric spectra and domain structure in the triglycine sulfate (TGS) hydrogen-containing ferroelectric under heating and cooling has been studied using the dielectric spectroscopy and atomic-force microscopy methods. The dielectric spectra are analyzed by the temperature-frequency dependences of the losses ε″ and by the temperature behavior of the maximum losses ε″max in the dispersion region at frequencies ranging from 102 to 106 Hz. A dynamic conductivity model is proposed for calculating temperature dependences of losses ε″max. The domain structure dynamics during the heating and cooling of the TGS crystal near the phase transition is studied using the in situ piezoresponse force microscopy. It is experimentally and theoretically shown that the relaxation dispersion is governed by the binding of strongly correlated dipoles with the main lattice that serves as a thermostat.

Physics of Wave Phenomena. 2017;25(3):231-237
pages 231-237 views

Generation of Electromagnetic Microwave Radiation

Particle-in-cell simulation of generation of an HF sequence of short current pulses in the vircator with counter-propagating beams

Dubinov A.E., Saikov S.K., Tarakanov V.P.

Abstract

We performed a particle-in-cell (PIC) simulation of a vircator with counter electron beams in a cylindrical cavity with metal walls. Two pairs of counter-propagating superlimiting electron beams with different energy and current in each pair are injected along the cylinder axis. It is found that the electron charge in the cavity is formed as a sequence of pulses corresponding to slow accumulation and fast discharge. It is shown that the pulses are related to the characteristic dynamics of the squeezed beam state, the distributed virtual cathode. This regime can be used to generate anHF sequence of ultrawideband electromagnetic pulses.

Physics of Wave Phenomena. 2017;25(3):238-241
pages 238-241 views

Erratum

Erratum to: “An enhanced refractive index with suppressed absorption in a graphene nanostructure under external magnetic field”

Raheli A., Hamedi H.R., Sahrai M.

Abstract

The Editorial Board apologizes for this error in the paper “An Enhanced Refractive Index with Suppressed Absorption in a Graphene Nanostructure under External Magnetic Field” by A. Raheli, H.R. Hamedi, and M. Sahrai.

Physics of Wave Phenomena. 2017;25(3):242-242
pages 242-242 views