Email this article Mixed-Ligand Coordination Compounds of Copper with Pyrocatechol Derivatives and 2-Hetarylbenzimidazoles
- Authors: Barskaya E.S.1, Moiseeva A.A.1, Beloglazkina E.K.1
-
Affiliations:
- Lomonosov Moscow State University
- Issue: Vol 122, No 2 (2024): THEMED SECTION: FUNDAMENTAL PRINCIPLES OF ORGANIC ELECTROCHEMISTRY, CREATION OF NEW FUNCTIONAL MATERIALS AND MATERIALS FOR MEDICINE
- Pages: 40-47
- Section: THEMED SECTION: FUNDAMENTAL SCIENTIFIC RESEARCH IN THE FIELD OF NATURAL SCIENCES
- URL: https://journal-vniispk.ru/1605-8070/article/view/303425
- DOI: https://doi.org/10.22204/2410-4639-2024-122-02-40-47
- ID: 303425
Cite item
Full Text
Abstract
Four new mixed-ligand copper-containing coordination compounds were synthesized, with the organic ligands, one of which (O,O-ligand) is bis-tert-butyl-substituted pyrocatechol, and the second (N,N-ligand) is 2-pyridylbenzimidazole or 2-imidazolylbenzothiazole. The structure of the obtained complexes was established based on the data of elemental analysis, electron spectroscopy, and electrochemical studies using cyclic voltammetry and rotating disk electrode voltammetry. It was shown that the resulting complexes with 2-pyridylbenzimidazole ligand contain Cu2+, and complexes with 2-imidazolylbenzothiazole contain Cu+.
About the authors
Elena S. Barskaya
Lomonosov Moscow State University
Author for correspondence.
Email: elenakovaleva2010@gamil.com
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991, Russia
Anna A. Moiseeva
Lomonosov Moscow State University
Email: moiseeva.1955@mail.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991, Russia
Elena K. Beloglazkina
Lomonosov Moscow State University
Email: beloglazki@mail.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991, Russia
References
- G. Speier, Z. Tyeklár, P. Tóth, E. Speier, S. Tisza, A. Rockenbauer, A. M. Whalen, N. Alkire, C. G. Pierpont Inorg. Chem., 2001, 40, 5653. doi: 10.1021/ic010373g.
- O.-S. Jung, C. G. Pierpont Inorg. Chem., 1994, 33, 2227. doi: 10.1021/ic00088a027.
- D.N. Hendrickson, C.G. Pierpont Spin Crossover in Transition Metal Compounds II, 2004, 234, 63. doi: 10.1007/b95413.
- A. Caneschi, A. Cornia, A. Dei Inorg. Chem., 1998, 37, 3419. doi: 10.1021/ic971083w.
- H. Ohtsu, K. Tanaka Angew. Chem. Int. Ed., 2004, 43, 6301. doi: 10.1002/anie.200460023.
- N. Shaikh, S. Goswami, A. Panja, X.-Y. Wang, S. Gao, R.J. Butcher, P. Banerjee Inorg. Chem., 2004, 43, 5908. doi: 10.1021/ic049579i.
- C. Drouz, M. Vlasiou, A.D. Keramidas Dalton Trans., 2013, 42, 11831. doi: 10.1039/C3DT50619C.
- K.P. Butin, E.K. Beloglazkin, N.V Zyk Russ. Chem. Rev., 2005, 74, 531. doi: 10.1070/RC2005v074n06ABEH000977.
- C.G. Pierpont, A.S. Attia Collect. Czech. Chem. Commun., 2001, 66, 33. doi: 10.1135/cccc20010033.
- G. Speier, S. Tisza, Z. Tyeklar, C.W. Lange, C.G. Pierpont Inorg. Chem., 1994, 33, 2041. doi: 10.1021/ic00087a047.
- F. Zhao, W. Wang, W. Lu, L. Xu, Sh.Yang, X.-M. Ca, M. Zhou, M. Lei, M. Ma, H.-J. Xu, F. Cao Eur. J. Med. Chem., 2018, 146, 451. doi: 10.1016/j.ejmech.2018.01.041.
- D. Dooley, M. McGuirl, D. Brown, P.N. Turowski, W.S. Mclntire, P.F. Knowles Nature, 1991, 349, 262. doi: 10.1038/349262a0.
- E.S. Barskaya, E.K. Beloglazkina, A.G. Mazhuga, I.V. Yudin, N.V. Zyk Russ. Chem. Bull., 2015, 64, 1975. doi: 10.1007/s11172-015-1103-3.
- E.S. Barskaya, V.V. Shorokhov, A.V. Rzheutsky, A.D. Khudyakov, I.V. Yudin, V.A. Tafeenko, N.V. Zyk, E.K. Beloglazkina Russ. Chem. Bull., 2019, 68, 638. doi: 10.1007/s11172-019-2468-5.
- T.M. Khomenko, O.V. Salomatina, S.Yu. Kurbakova, I.V. Il’ina, K.P. Volcho, N.I. Komarova, D.V. Korchagina, N.F. Salakhutdinov, A.G. Tolstikov Russ. J. Org. Chem., 2006, 42, 1653. doi: 10.1134/S1070428006110091.
Supplementary files
