Ammonia decomposition on a platinum nanocoating at various electric potentials

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Abstract

It was shown that the rate of ammonia decomposition on a platinum nanocoating can be controlled by applying an external electrostatic field to the coating to create a negative or positive platinum potential of variable magnitude. In experiments conducted with a contact time of 15 min between platinum and ammonia at a temperature of 700 K and a pressure of 5 × 10–7 Torr, the decomposition rate increased by 44% at a negative potential of the coating of–6 V and by 70% at a positive potential of +6 V.

About the authors

M. V. Grishin

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Russian Federation, Moscow

A. K. Gatin

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Russian Federation, Moscow

V. G. Slutskii

Semenov Institute of Chemical Physics

Author for correspondence.
Email: slutsky@center.chph.ras.ru
Russian Federation, Moscow

V. A. Kharitonov

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Russian Federation, Moscow

S. A. Tsyganov

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Russian Federation, Moscow

B. R. Shub

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Russian Federation, Moscow

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