Kinetic isotope H/D effect in the oxidation of ethers of linoleic acid in solutions

I. V. Tikhonov; I. V. Moskalenko; E. M. Pliss; M. A. Fomich; A. V. Bekish; V. V. Shmanai

doi:10.1134/S1990793117030113

Kinetic isotope H/D effect in the oxidation of ethers of linoleic acid in solutions

Authors: Tikhonov I.V.¹, Moskalenko I.V.¹, Pliss E.M.¹, Fomich M.A.², Bekish A.V.³, Shmanai V.V.²
Affiliations:
1. Demidov Yaroslavl University
2. Institute of Physical Organic Chemistry
3. Belarus State University
Issue: Vol 11, No 3 (2017)
Pages: 395-399
Section: Kinetics and Mechanism of Chemical Reactions. Catalysis
URL: https://journal-vniispk.ru/1990-7931/article/view/199177
DOI: https://doi.org/10.1134/S1990793117030113
ID: 199177

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

It is shown that the initiated oxidation of deuterated esters of linoleic acid proceeds as a radical chain process. The value of the kinetic isotope effect for hydrogen atom abstraction from the bisallyl group of linoleic acid esters is determined: 3.0 for tert-butyl peroxy and cumylperoxy radicals.