Email this article Superoxide radicals in the kinetics of nitroxide-inhibited oxidation of methyl linoleate in micelles
- Authors: Pliss E.M.1, Borodin L.I.1, Sen’ V.D.1,2, Tikhonov I.V.1
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Affiliations:
- Demidov Yaroslavl State University
- Institute of Problems of Chemical Physics
- Issue: Vol 11, No 3 (2017)
- Pages: 400-402
- Section: Kinetics and Mechanism of Chemical Reactions. Catalysis
- URL: https://journal-vniispk.ru/1990-7931/article/view/199178
- DOI: https://doi.org/10.1134/S1990793117030253
- ID: 199178
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Abstract
The kinetics of the oxidation of methyl linoleate in micelles inhibited by stable nitroxides under the conditions of initiation by superoxide radicals was studied. Multiple breakdown of the oxidation chains was observed in this process. The antioxidant activity of nitroxides increased when the reduction potential of the oxoammonium cation/nitroxide pair decreased and their lipophilicity increased.
About the authors
E. M. Pliss
Demidov Yaroslavl State University
Author for correspondence.
Email: e.pliss@mail.ru
Russian Federation, Yaroslavl, 150000
L. I. Borodin
Demidov Yaroslavl State University
Email: e.pliss@mail.ru
Russian Federation, Yaroslavl, 150000
V. D. Sen’
Demidov Yaroslavl State University; Institute of Problems of Chemical Physics
Email: e.pliss@mail.ru
Russian Federation, Yaroslavl, 150000; Chernogolovka, Moscow oblast, 142432
I. V. Tikhonov
Demidov Yaroslavl State University
Email: e.pliss@mail.ru
Russian Federation, Yaroslavl, 150000
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