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Quasi-Hydrostatic Model of the Combustion of Compositions Forming Molten Reaction Products in the Presence of Centrifugal Forces


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Abstract

A mathematical model of the exothermic chemical transformation of a high-calorie mixture in the presence of centrifugal forces is considered. The process is studied for the 3NiO + (2 + α)Al → Al2O3 + (3 − α)Ni + αNiAl thermite composition, as an example. Such processes are used in high-temperature synthesis for the production of target products in the combustion wave propagating through the initial mixture. This technological process represents a combination of high-temperature combustion with the formation of liquid products, their separation, and subsequent cooling. A distinctive feature of the proposed model is the use of a “through” description, which makes it possible to examine the mutual influence of the individual stages on the dynamics of the process. This feature provides a more realistic description of the actual process.

About the authors

K. G. Shkadinskii

Institute of Problems of Chemical Physics; Institute of Structural Macrokinetics and Materials Science

Author for correspondence.
Email: shkad@ficp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432; Chernogolovka, Moscow oblast, 142432

N. I. Ozerkovskaya

Institute of Structural Macrokinetics and Materials Science

Email: shkad@ficp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

P. M. Krishenik

Institute of Structural Macrokinetics and Materials Science

Email: shkad@ficp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

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