Copper(II) Chloride-Catalyzed Oxidation of a Styrene Oxide–Aniline Binary System in a Polar Solvent


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Abstract

In a mixed tert-butanol–chlorobenzene (9 : 1 vol) solution, the consumption of oxygen by a styrene oxide–aniline–copper(II) chloride ternary system is studied. For the first time, the formation of free radical particles is detected in copper(II) salt-catalyzed reaction of styrene oxide with the amine.

About the authors

L. V. Petrov

Institute of Problems of Chemical Physics

Author for correspondence.
Email: plv@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

V. M. Solyanikov

Institute of Problems of Chemical Physics

Email: plv@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

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