Thermodynamic Conditions of the Rehbinder Effect and Dependence of the Adsorption Effect on Electric Potential of a Solid Surface and Adsorbate Concentration

Abstract

Thermodynamic conditions of the Rehbinder effect and the dependence of adsorption effect on the electric potential of the solid phase and volume concentration of adsorbate are analytically studied in the framework of the theory of single-component adsorption from a liquid on a solid surface in the presence of an electric charge on the surface and taking into account the surface deformation proposed earlier. These conditions and general dependences are supplemented with detailed analysis for the case of adsorption according to the Temkin isotherm.