Effect of Iron sulfate as electrolyte additive on plasma electrolytic oxidation of aluminum alloy

Abstract

This study has been carried out to investigate the incorporation of Iron(II) sulfate as an additive of electrolyte on formed AA1010 aluminum alloy, using plasma electrolytic oxidation method in silicate-based electrolytes containing Iron(II) sulfate. In order to fabricate nanocomposite coating, silicon nitride nanopowder was added to electrolyte. The effects of iron(II) sulfate additive on the voltage-time trend, microstructure, compositions, wear, and corrosion resistances of PEO coatings were investigated. In addition, current density and concentration of additive were studied as parameters that were effective on coating. Results showed that although FeSO₄ enters to the coating structure, but it does not develop a new phase. The corrosion and wear behavior of coated samples with FeSO₄ indicate an improvement as compared to those without additive.