Study of inhibition effect of carboxylic salt derivative on corrosion of C1010 carbon steel in saline solution

Abstract

In the present work, sodium 4-[(4-formylbenzylidene) amino] benzoiate (4) was synthesized and its structure was confirmed using spectroscopic techniques. Prepared compound was successfully applied as a corrosion inhibitor for C1010 carbon steel in 3.5% NaCl solution at 25°C. Different electrochemical measurements such as linear polarization resistance (LPR), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) were used to evaluate the suggested inhibitor (4). The results of different electrochemical measurements show that inhibition efficiencies obtained from EIS curves are in consistence with the results of potentiodynamic polarization and LPR measurements due to increase corrosion inhibition efficiency by increasing the concentration of organic inhibitor (4). Semi-empirical calculations with PM3 method were used to find relationship between molecular structure and inhibiting effect of suggested inhibitor (4).