A Study of a Novel Nanocomposite Material Based on Reduced Graphene Oxide and Poly(o-Phenylenediamine)


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Abstract

The formation of a nanocomposite coating based on reduced graphene oxide (RGO) and poly(o-phenylenediamine) (PPD) in the chemical reaction of graphene oxide (GO) and o-phenylenediamine (OPD) has been studied by cyclic voltammetry (CVA), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). It has been shown that the action of cyclic polarization provides a more uniform structure of the nanocomposite films (decrease in the corrugation effect). In addition, it has been found that the polarization of GO films containing the OPD monomer distributed inside to the PPD synthesis potentials leads to the formation of uniformly distributed globular structures, which most probably correspond to a polymer electrochemically synthesized in the space between the GO nanosheets.

About the authors

E. Yu. Pisarevskaya

Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: elena_pisarevska@bk.ru
Russian Federation, Moscow, 119071

Yu. B. Makarychev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: elena_pisarevska@bk.ru
Russian Federation, Moscow, 119071

N. N. Dremova

Institute of Problems of Chemical Physics

Email: elena_pisarevska@bk.ru
Russian Federation, Moscow oblast, Chernogolovka, 142432

G. P. Girina

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: elena_pisarevska@bk.ru
Russian Federation, Moscow, 119071

O. N. Efimov

Institute of Problems of Chemical Physics

Email: elena_pisarevska@bk.ru
Russian Federation, Moscow oblast, Chernogolovka, 142432

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