A Study of a Novel Nanocomposite Material Based on Reduced Graphene Oxide and Poly(o-Phenylenediamine)
- Authors: Pisarevskaya E.Y.1, Makarychev Y.B.1, Dremova N.N.2, Girina G.P.1, Efimov O.N.2
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Problems of Chemical Physics
- Issue: Vol 54, No 3 (2018)
- Pages: 393-401
- Section: Nanoscale and Nanostructured Materials and Coatings
- URL: https://journal-vniispk.ru/2070-2051/article/view/204002
- DOI: https://doi.org/10.1134/S2070205118030127
- ID: 204002
Cite item
Abstract
The formation of a nanocomposite coating based on reduced graphene oxide (RGO) and poly(o-phenylenediamine) (PPD) in the chemical reaction of graphene oxide (GO) and o-phenylenediamine (OPD) has been studied by cyclic voltammetry (CVA), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). It has been shown that the action of cyclic polarization provides a more uniform structure of the nanocomposite films (decrease in the corrugation effect). In addition, it has been found that the polarization of GO films containing the OPD monomer distributed inside to the PPD synthesis potentials leads to the formation of uniformly distributed globular structures, which most probably correspond to a polymer electrochemically synthesized in the space between the GO nanosheets.
About the authors
E. Yu. Pisarevskaya
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: elena_pisarevska@bk.ru
Russian Federation, Moscow, 119071
Yu. B. Makarychev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: elena_pisarevska@bk.ru
Russian Federation, Moscow, 119071
N. N. Dremova
Institute of Problems of Chemical Physics
Email: elena_pisarevska@bk.ru
Russian Federation, Moscow oblast, Chernogolovka, 142432
G. P. Girina
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: elena_pisarevska@bk.ru
Russian Federation, Moscow, 119071
O. N. Efimov
Institute of Problems of Chemical Physics
Email: elena_pisarevska@bk.ru
Russian Federation, Moscow oblast, Chernogolovka, 142432
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