Inhibition of Copper Corrosion in Binary Acid Mixtures (HNO3 + H3PO4) using Tamarix Boveana Plant Extract

Abstract

In this study, the inhibition effect of Tamarix Boveana (TB) extract on Cu corrosion in 1 mol L^–1 (HNO₃ + H₃PO₄) mixture was studied. Electrochemical techniques such as (potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM)) and non-electrochemical technique such as mass loss were used. Results showed that TB extract has good inhibition efficiency (IE), follows Langmuir adsorption isotherm and all of the methods are in good agreement. The IE increased by increasing the concentration of the extract and decreased by increasing the temperature so, the extract adsorbed on Cu surface physically. The IE depends on the concentration of the extract and reaches 73.5% at 300 ppm of the extract. PP results revealed that the (TB) extract doings as mixed type one. Surface analysis revealed that the extract components are adsorbed on Cu surface forming a film.