Email this article The Influence of High Reactivity of Diaryl Telluroxides on Their Chromatography/Mass Spectrometry Identification Data
- Authors: Eliseeva E.V.1, Red’kin N.A.1, Gar’kin V.P.1, Pytskii I.S.2, Buryak A.K.2
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Affiliations:
- Korolev Samara National Research University
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 55, No 6 (2019)
- Pages: 1242-1248
- Section: Investigation Methods for Physicochemical Systems
- URL: https://journal-vniispk.ru/2070-2051/article/view/205702
- DOI: https://doi.org/10.1134/S2070205119060108
- ID: 205702
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Abstract
The identification features of symmetric and nonsymmetric diaryl telluroxides via chromatography/mass spectrometry with electrospray ionization (HPLC/MS-ESI) are studied in the present work. Diaryl telluroxides exposed to ESI are shown to give rise to the formation of dimer ions and associate ions with the mobile phase components. Moreover, the influence of analyte concentration in the solution and the injection volume is found to impact the chromatography/mass spectrometry data.
About the authors
E. V. Eliseeva
Korolev Samara National Research University
Author for correspondence.
Email: eveletskaya@gmail.com
Russian Federation, Samara, 443086
N. A. Red’kin
Korolev Samara National Research University
Email: eveletskaya@gmail.com
Russian Federation, Samara, 443086
V. P. Gar’kin
Korolev Samara National Research University
Email: eveletskaya@gmail.com
Russian Federation, Samara, 443086
I. S. Pytskii
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: eveletskaya@gmail.com
Russian Federation, Moscow, 119071
A. K. Buryak
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: eveletskaya@gmail.com
Russian Federation, Moscow, 119071
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