


Vol 9, No 6 (2018)
- Year: 2018
- Articles: 32
- URL: https://journal-vniispk.ru/2075-1133/issue/view/12894
Metal Sciences. Metallurgy
Structure Changes of High-Strength Economically Alloyed Steel 09KhGN2MD (09CrMnNi2MoCu) In Tempering
Abstract
The purpose of the present investigation is to determine the heat treatment parameters that ensure yield strength over 690 MPa in combination with toughness of at least 35 J/cm2 at temperature of –70°C in new economically alloyed cold-resistant steel. The effect of various quenching and tempering parameters on mechanical properties, structure of steel, and fracture mode of samples after impact tests at temperature of –70°C has been studied. The relationship between the properties, structure, and fracture mode of steel samples is shown. The heat treatment parameters of the investigated steel are determined.



Carburization of Heat-Exchanger Pipes of 09Kh18N9 Grade Steel in Contact with Sodium Coolant
Abstract
The carburization process of heat-exchanger piping of 09Kh18N9 grade steel in contact with sodium coolant under conditions of long-term service at 515°С has been investigated. An effective diffusion coefficient has been determined on the basis of the experimental data on carbon concentration in the metal surface layer; the carburization depth within the temperature range 450–515°С has been calculated.



Refractory Monocarbides and Diborides of Transition Metals: Promising Components of High-Temperature Composite Materials
Abstract
Abstract—Development of innovative composite materials capable of operating under extreme conditions requires a comprehensive engineering approach. One of the components of such materials can be represented by monocarbides and diborides of transition metals of groups IV–VI of the periodic table: titanium, zirconium, hafnium, vanadium, niobium, tantalum, as well as their binary systems. Most isomorphic pairs of monocarbides and ddiborides are characterized by unlimited mutual solubility. The HfC–TaC system is of particular interest. The melting point of TaC–4HfC exceeds 4000°C, which is the highest refractoriness among all known synthesized substances.



Concentration Redistribution of Alloying Elements in Pseudo-Alpha-Titanium Alloy under Elastoplastic Deformation
Abstract
The paper studies redistribution of alloying elements (Al, V, Mo) in the pseudo-alpha-titanium structure under graded stretching until destruction of the sample. Local sections of the titanium structure and of the fracture surface have been scanned by electron microscopy and X-ray microanalysis. The change in the chemical and phase composition of the alloy has been compared with the initial state stimulated by deformation impact. The structural-phase state of the material under high plastic strains is metastable, fixed by the system of deformation defects of the crystal lattice.



Research on Submicron-Grained Structure Formation in Titanium Alloys upon Reversible Hydrogenation and Plastic Deformation
Abstract
Abstract—The influence of thermohydrogen treatment combined with hot rolling on the structural formation in α- and near-α-titanium alloys has been studied. The prospects of obtaining submicron-grained sheet semifinished products of VT5 (Ti–5.8Al–0.1Fe, wt %) and VT20 (Ti–5.9Al–1.5V–1.2Mo–1.8Zr–0.1Fe, wt %) alloys are shown. In these materials, a submicron-grained structure allows the plastic deformation to be induced by superplasticity at temperatures reduced by 100–200°С.



Structural Features of Niobium Carbide Disperse Particles in the Structure of Heat-Resistant Alloys Based on Fe–25Cr–35Ni System
Abstract
Abstract—The structure of hardening niobium carbide particles in a cast heat-resistant alloy based on the Fe–Cr–Ni–C system modified with Nb and Ti is studied by means of optical and electron microscopy. It is established that the particles of niobium carbide in the structure of the cast alloy can be considered as multiphase polycrystalline clusters that are heterogeneous in chemical composition and crystalline structure. Possible reasons for a complicated polycrystalline structure of niobium carbide particles are presented.



Development of Ni-Base Superalloy with Operating Temperature up to 800°C for Gas Turbine Disks
Abstract
Abstract—The results of development of new nickel-base superalloy having an operating temperature up to 800°C for gas turbine disks have been presented. Structures, mechanical properties, and phase transformations of six experimental compositions have been researched. Physical and chemical modeling has been used to make a right choice of an alloy; with parameters as composition equivalents (they were based on equations of nonpolarizing ionic radii). The highest level of strength, ductility, toughness, and heat resistance was exhibited at 750°C by the Ni–Co–Cr–W–Mo–Ta–Al–Ti–Nb experimental composition with the total of aluminum, titanium, and niobium equal to 10 wt % and containing 4 wt % of tantalum.



Influence of Hot Plastic Deformation Modes on the Structure and Properties of Quenched Hot Rolled Economically Alloyed High-Strength Steel
Abstract
Abstract—The peculiarities of the structure formation of low-carbon high-strength economically alloyed steel with guaranteed yield strength of 750 MPa are studied using EBSD analysis after hot plastic deformation an various temperatures simulated on a GLEEBLE 3800 plastometer. A comprehensive approach includes the estimation of the size of hardness austenite grains and their heterogeneity, as well as the construction of size distribution histograms of structural elements and angles of misorientations between them. The relative extent of small-angle boundaries is analyzed as well. The results are confirmed by study of sheet metal of thickness up to 40 mm manufactured under industrial conditions.



Structure Formation of the Nitrogen-Containing Austenitic 04Kh20N6G11M2AFB Steel at Hot Deformation: Part I. Influence of Deformation Temperature and Strain Rate on the Process of Dynamic Recrystallization
Abstract
This work determines the values of the deformation threshold necessary for the initiation and development of dynamic recrystallization within the investigated deformation temperature and strain rate for high-strength corrosion-resistant nitrogen-containing austenitic 04Kh20N6G11M2AFB steel. Analysis of diagrams shows that the deformation resistance increases with the decrease in the deformation temperature. A faint peak is observed at 1000–1200°C; it indicates the start of dynamic recrystallization. The structure of high-strength corrosion-resistant nitrogen-containing austenitic 04Kh20N6G11M2AFB steel after hot deformation with the strain rate of 0.1, 1.0, and 10 s–1 within the temperature range of 900–1200°С is studied by the EBSD analysis and transmission electron microscopy.



Structure Formation of the Nitrogen-Containing Austenitic 04Kh20N6G11M2AFB Steel at Hot Deformation: Part II. Influence of the Phase Composition and Conditions of Hot Deformation on the Process of Dynamic Recrystallization
Abstract
The impact of δ-ferrite in high-strength corrosion-resistant nitrogen-containing 04Kh20N6G11M2AFB steel on deformation resistance during hot deformation within the temperature range of 900–1200°С and strain rates of 0.1–10 s–1 was investigated. Analysis of diagrams shows that dynamic recrystallization of δ-ferrite steel starts at a lower threshold deformation rate compared with pure austenitic steel. The values of the deformation threshold necessary for the initiation and development of dynamic recrystallization depending on the phase composition of the nitrogen-containing steel were determined. The complex analysis of the structure proved that δ-ferrite contributes to the nucleation and development of dynamic recrystallization at 1200–1000°C (its initiation corresponds to the lowest deformation threshold) and formation of the recrystallized structure in a larger volume as compared with the purely austenitic structure.



Structure and Properties of the Heat-Affected Zone of Low-Alloy Cold-Resistant Steel for Arctic Application
Abstract
Abstract—The paper presents the results of a comprehensive study of structural and property changes in the most dangerous regions of the heat-affected zone of low-alloy cold-resistant steel with a guaranteed yield strength of 355–390 MPa before and after the post-welding tempering, including those caused by the combined impact of heating temperature under tempering and deformation, compared to base metal. The simulation was performed using a DIL 805 dilatometer and a Gleeble 3800 complex. The results of the investigation of the structure and properties of actual welded joints after welding with different rates of energy input (3.5 and 6 kJ/mm) are presented.



Functional Materials
Features of Thermal Effects of Coatings Fabricated by Cold Gas Dynamic Spraying under Thermal Load
Abstract



Wear- and Corrosion-Resistant Functionally Gradient Coatings Based on Composite Powders of Metal–Nonmetal System
Abstract
The technology of formation of wear- and corrosion-resistant functionally gradient coatings by a method of microplasma sputtering of composite nanostructured powders was developed. The microhardness of obtained coatings reaches 10.27 GPa, providing effective protection of parts and components of precision engineering in extreme operating conditions.



Cast Microwire with High Value of Thermoelectromotive Force
Abstract
The paper considers specific features of the process of casting of microwires by high-speed melt quenching. The conditions for selecting a metal–glass pair are determined to achieve the required technological and mechanical properties of microwires. The alloy of the Cu–Zr–Si–B system is investigated and its optimal composition is determined, which seems promising for casting of microwires with high thermoelectromotive force (thermo-emf) using standard technology. The thermoelectric power of the obtained microwires is more than 40 μV K–1, showing great promise for manufacturing of microthermocouples.



Polymer Composite Materials
Heat-Resistant Electrical Insulating Fiberglass Plastics for Shipbuilding
Abstract
Abstract—Heat resistance of fiberglass plastics depends mostly on heat resistance of the polymer matrix (binder) and technological modes of production. Increasing the heat resistance and strength of electric insulation makes it possible to improve the properties of electric machines and prolong their working life. Hot pressing technology was developed and fiberglass plastic articles for electric insulation of parts of the ship propulsion complex (main and servicing diesel generators, turbo generators, electric motors) were manufactured. Exploitation modes were settled for electric insulation from different types of binders and reinforcing materials based on alkali-free, quartz, and siliceous high modulus and high strength glass fibers.



Epoxy Vinyl Ester Binder for Fire-Resistant Marine Fiberglass Plastics
Abstract
Abstract—The article deals with the problem of fire resistance for resins used in shipbuilding; the results of researching incombustible phosphorus epoxy vinyl ester resin VE-PHAS and vinyl ester binder are given. In addition, the properties of resin in accordance with curing system content, mechanical properties of fiberglass plastic based on VE-PHAS, and fire safety are presented.



Researching the Interface of Polymer Matrices with Optical Fibers in Smart Materials
Abstract



Temperature and Frequency Dependences of Dissipative Properties of Rigid Vibration-Damping Coatings
Abstract
Abstract—A study of the temperature and frequency dependences of the mechanical loss factors and elastic moduli of polymeric materials allows one to calculate the efficiency of vibration-damping coatings on substrates of metals and rigid composites under specified operating conditions. The calculated and experimental data for different compositions of vibration-damping materials are compared. The studies are performed using polymer compositions on the basis of modified epoxy resins and reinforcing fillers.



Welding and Allied Processes. Welding Consumables and Technologies
Improvement of the Service Properties of the Weld Joint Metal for Transport Nuclear Power Units Manufactured of Heat-Resistant Steel Grades: Part I. Technology of Welding Heat-Resistant Steel Grades Using Low-Carbon Welding Materials without Heat Treatment and Experience of Applying Welding Materials
Abstract
The paper describes a technology for welding the assembly joints in power plants of nuclear icebreakers manufactured of heat-resistant 15Cr2MoV steel grades using low-carbon surfacing. The proposed technology is a reliable method for assuring the serviceability of icebreaker nuclear power plants under conditions when the heat treatment of the assembly joint is infeasible. The low-carbon all-weld metal is often prone to softening under the action of repeated process tempering cycles to which the assembly units of the equipment are subjected.



Improvement of the Service Properties of the Weld Joint Metal for Transport Nuclear Power Units Manufactured of Heat-Resistant Steel Grades: Part II. A Study of Mechanical Properties of Low-Carbon Weld Deposits Depending on the Welding Process Variables
Abstract



Improvement of the Service Properties of the Weld Joint Metal for Transport Nuclear Power Units Manufactured of Heat-Resistant Steel Grades: Part III. A Study of the Influence of Alloying Elements on the Characteristics of the All-Weld Metal as Applied to the Fabrication of Low-Carbon Metal Deposits and Assembly Weld Joints in Icebreaker Nuclear Power Units
Abstract
The influence of alloying elements, namely, silicon, manganese, nickel, and molybdenum, contained in the welding wire on the mechanical properties of the metal of automatic submerged-arc welding joints has been investigated. It has been established that the required strength and ductility values and the ductile-to-brittle transition temperature of the weld metal both in the as-welded state and upon high-temperature tempering are achieved by using welding wire with a silicon content of ~0.6% and a manganese content of ~1.5%.



Effect of Boron Microalloying on the Structure and Properties of a Welded Joint Made of a Flux-Cored Wire for Welding of Flat-Rolled High-Strength Steel Plates with a Standard Yield Stress of 750 MPa
Abstract
Abstract—The effect of the boron microalloying on the structure and mechanical properties of a weld of high-strength steel with a standard yield stress of 750 MPa has been studied. On the basis of the results, a flux-cored wire of brand 48PP-69 has been developed.



Calculation of Thermal Processes around Moving Molten Pool Using Boundary Element Method
Abstract
Abstract—A technique for the calculation of the steady-state temperature field in a solid part of a welded workpiece has been developed by using a moving weld pool size as input data and a boundary element method for solving the heat conduction problem. The technique allows one to calculate the effective power and thermal efficiency of a heat source. An example of a through-penetration arc welding with a tungsten electrode for the case of a 4-mm-thick aluminum alloy 1565chMU reveals the temperature gradient distributions and cooling rate at the pool boundary. A good agreement is observed between the calculated and experimental thermal cycles. The distribution of hardness in the cross section of a butt weld is presented.



Corrosion and Protection of Metals
Effect of Interstitial Elements on Pitting and Intercrystalline Corrosion of Austenitic Chromium-Nickel Steel
Abstract
Abstract—The possibility of improving the resistance of austenitic chromium-nickel steel of 09Kh18N9 and 08Kh16N11М3 grades to pitting and intercrystalline corrosion under the conditions of standby mode of a fast neutron reactor facility has been investigated. Corrosion tests lasting up to 15 000 h have demonstrated that the corrosion rate decreases significantly upon the decrease in the carbon content and the increase in the nitrogen content.



Some Aspects of Studying the Corrosion Processes in 25Kh1MF Steel Fasteners after Aluminizing
Abstract
Abstract—The resistance to atmospheric corrosion of 25Kh1MF steel after aluminizing and thermal improvement has been studied. It is established that the low resistance of the aluminized layer to atmospheric corrosion is caused by surface defects, such as cracks and the pores, or by the partial removal of the layer containing the Fe3Al intermetallic. In the aluminized layer containing ferrite doped with aluminum, aluminum nitrides that prevent the cold diffusion welding of mating thread surfaces of fasteners are found.



Radiation Materials Science
Synergistic Mechanism of Radiation Embrittlement of Austenitic Stainless Steels under Long-Term High-Temperature Irradiation
Abstract
Abstract—The results of studying the mechanisms of fracture and embrittlement of the Kh18N9 and Kh18N10T austenitic steels under long-term neutron irradiation at elevated temperatures are given. The effects of the temperature and time of irradiation and the neutron radiation dose on the fracture strain and fracture mechanisms are analyzed. On the basis of the results obtained and specially performed experiments, a synergistic mechanism of embrittlement of the material under conditions of long-term high-temperature irradiation is proposed and substantiated, which is determined by the following two factors: thermal aging and helium diffusion. The thermal aging leads to the formation of various phases at grain boundaries and, hence, to a decrease in the grain boundary strength. Helium diffusion at elevated temperatures gives rise to the accumulation and growth of helium bubbles at weakened grain boundaries.



Influence of Neutron Irradiation and Post-Irradiation Annealing on Mechanical Properties and Fracture Toughness of the Anticorrosive Cladding for VVER-Type Reactors: Part 1. Mechanisms of Embrittlement and Recovery of Cladding Properties
Abstract
Abstract—The influence of neutron irradiation and post-irradiation annealing on the fracture toughness of anticorrosive cladding material for reactor pressure vessels with different phosphorus and δ-ferrite content was investigated. The effect of the annealing temperature on the degree of degradation and recovery of the weld metal was considered. The processes during annealing exerting both positive and negative effects on recovery of the cladding properties were studied. The results of the research can be used for justification of the resistance to brittle fracture of reactor pressure vessels after annealing.



Influence of Neutron Irradiation and Post-Irradiation Annealing on Mechanical Properties and Fracture Toughness of Anticorrosive Cladding for VVER-Type Reactors: Part 2. Predictive Modeling of the Mechanical Properties and Fracture Toughness of Cladding
Abstract
Abstract—The influence of neutron irradiation, post-irradiation annealing, and re-irradiation on the fracture toughness and mechanical properties of anticorrosive cladding material for reactor pressure vessels was investigated. Dependences for predicting the deformation diagram and fracture toughness of the weld metal, with the consideration of the effect of annealing and repeated neutron irradiation were proposed. The obtained curves may be used to calculate the stress-strain state of reactor pressure vessels, as well as to assess the brittle fracture of the material during operation of the reactor vessel after annealing.



Study of Steel Corrosion Cracking Mechanisms for VVER RPV Internals Based on Simulation Tests
Abstract
Different hypotheses of irradiation assisted stress corrosion cracking for materials of internals in the light water reactor environment were analyzed. Irradiation-induced grain boundary chromium depletion, localized deformation, and material hardening were considered. Heat treatment and cold working of 18Cr–10Ni–Ti steel were made to simulate the influence of neutron irradiation. Autoclave tests in the light water reactor environment at a temperature 290°C and at a strain rate of 3 × 10–7 s–1 were carried out. 18Cr–10Ni–Ti steel specimens in the initial state, after heat treatment, and after heat treatment followed by cold working were used. Fracture surfaces and lateral surfaces of specimens were examined by scanning electron microscopy. The microstructure of the material was also examined using transmission electron microscopy. It was shown that the grain boundary chromium depletion and the material hardening are not the main causes of corrosion cracking of 18Cr–10Ni–Ti steel in the primary coolant deoxygenated environment. The localization of deformation has a profound effect on corrosion cracking in the absence of the grain boundary sliding. The conditions determining the crack propagation by the corrosion cracking mechanism are defined.



Improvement of the Approach to Predict the Fracture Toughness of Irradiated Anticorrosive Cladding for WWER-Type Reactors
Abstract
Abstract—The paper presents the results of experimental investigations on the fracture toughness of anticorrosive cladding for the reactor pressure vessel of WWER-type reactors after irradiation in a range from 0 to 1.8 × 1020 neutron/cm2. On the basis of these data and results obtained earlier, the fracture toughness is derived by statistical analysis methods as a function of neutron fluence and test temperature.



Simulation of Materials and Technological Processes
Mathematical Modeling of Stress–Strain State in Titanium Alloys Considering the Microstructure and Crystal Orientation Measured by EBSD
Abstract
Abstract—The virtual structures of titanium alloy fragments are created via EBSD using microstructural research and local crystal orientations. The uniaxial strains are calculated through a finite element method taking crystallographic characteristics, anisotropic elastic moduli, and crystallographic sliding into account. The mapping of the Schmid factor is carried out for structural fragments. The influence of measured orientations on the intensity of theoretical stress and strains in the loaded elements of polycrystalline material is studied as well.



Structural and Technological Strength and Efficiency of Materials
Construction of Theoretical Curves of the Long-Term Strength for Neutron-Irradiated Austenitic Steels Kh18N9 and 08Kh16N11M3
Abstract
Abstract—Having analyzed experimental data on the long-term strength of unirradiated austenitic materials and predictive dependences obtained in the context of a physical and mechanical model of intergranular fracture, the authors have determined the assurance factor for plotting the long-term strength curves for unirradiated and irradiated materials. The above model, as well as experimental results, has made it possible to calculate the normative curves for the initial and irradiated steels Kh18N9 and 08Kh16N11M3. Their validity has been verified on the basis of external and intrareactor tests.


