Sensitivity of salts of 5,5′-azotetrazole with nitrogenous bases, their crystalline hydrates, and mixtures with oxidants to detonation pulse

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

High-energy salts of 5,5′-azotetrazole with nitrogeneous bases are the promising components for a wide range of energy-enchanced materials. The sensitivity to detonation pulse of 5,5′-azotetrazole salts with nitrogenous bases, crystalline hydrates of 5,5′-azotetrazole salts, and mixtures of 5,5′-azotetrazole salts with oxidants in small diameter charges was studied by determining the minimal initiating charge of triaceton triperoxide and hexamethylene triperoxydiamine. The minimum initiating charges were determined, the influence of crystallization water and oxidizers was shown, and the critical diameter of detonation of the studied substances was estimated.

Full Text

Restricted Access

About the authors

Iiya V. Lazarev

D. I. Mendeleev University of Chemical Technology of Russia

Author for correspondence.
Email: fonarnyistolb@gmail.com

student

Russian Federation, 9 Miusskaya Sq., Moscow 125047

Anton I. Levshenkov

D. I. Mendeleev University of Chemical Technology of Russia

Email: antlew@rambler.ru

Candidate of Science in chemistry, assistant professor

Russian Federation, 9 Miusskaya Sq., Moscow 125047

Ludmila E. Bogdanova

D. I. Mendeleev University of Chemical Technology of Russia

Email: akhapkina-luda@rambler.ru

engineer

Russian Federation, 9 Miusskaya Sq., Moscow 125047

References

  1. Thiele, J. 1989. Ueber Azo- und Hydrazoverbindungen des Tetrazols. Liebigs Ann. 303:57–78.
  2. Hiskey. M. A., N. Goldman, and J. R. Stine. 1998. High nitrogen energetic materials derived from azotetrazolate. J. Energ. Mater. 16:119–127.
  3. Hammerl, A., T. M. Klapotke, H. Noth, and M. Warchhold. 2001. [N2H5]2+[N4C–N=N–CN4]2-: A new high-nitrogen high-energetic material. Inorg. Chem. 40:3570–3575.
  4. Sivabalan, R., M. B. Talawar, N. Senthilkumar, B. Kavitha, and S. N. Asthana. 2004. Studies on azotetrazolate based high nitrogen content high energy materials potential additives for rocket propellants. J. Therm. Anal. Calorim. 78:781–791.
  5. Hammerl, A., M. A. Hiskey, G. Holl, T. M. Klapotke, K. Polborn, J. Stierstotfer, and J. J. Weigand. 2005. Azidoformamidium and guanidinium 5,5′-azotetrazolate salts. Chem. Mater. 17:3784–3793.
  6. Sivabalan, R., M. Anniyappan, S. J. Pawar, M. B. Talawar, G. M. Gore, S. Venugopalan, and B. R. Gandhe. 2006. Synthesis, characterization and thermolysis studies on tiazole and tetrazole based high nitrogen content high energy materials. J. Hazard. Mater. 137(2):672–680.
  7. Tappan, B. C., A. N. Ali, S. F. Son, and T. B. Brill. 2006. Decomposition and ignition of the high-nitrogen compound triaminoguanidinium azotetrazolate. Propell. Explos. Pyrot. 31:163–167.
  8. Akhapkina, L. E., P. A. Postnikov, Min Tant M’e, A. I. Levshenkov, and V. P. Sinditskii. 2011. Sintez i issledovanie soley 5,5′-azotetrazola s azotistymi osnovaniyami [Synthesis on investigation of 5,5′-azotetrazole salts]. Uspekhi v khimii i khimicheskoy tekhnologii [Advances in Chemistry and Chemical Technology] 25(12):54–58.
  9. Levshenkova, L. E., V. P. Sinditskii, and A. I. Levshenkov. 2013. Issledovanie termicheskogo raspada guanidinovoy i ammonievoy soley 5,5′-azotetrazola [Study of thermal decomposition of guanidinium and ammonium 5,5′-azotetrazole salts]. Uspekhi v khimii i khimicheskoy tekhnologii [Advances in Chemistry and Chemical Technology] 27(2):131–136.
  10. Levshenkova, L. E., N. A. Muriljov, W. H. Aung, A. I. Levshenkov, and V. P. Sinditskii. 2015. Raspad onievykh soley 5,5′-azotetrazola v zhidkoy faze [The decomposition of onium 5,5′-azotetrazole salts in liquid]. Uspekhi v khimii i khimicheskoy tekhnologii [Advances in Chemistry and Chemical Technology] 29(8):53–55.
  11. Levshenkova, L. E., and A. I. Levshenkov. 2015. Sintez i svoystva soley 5,5′-azotetrazola s azotistymi osnovaniyami [Synthesis on investigation of 5,5′-azotetrazole salts]. Vestnik Buryatskogo gosudarstvennogo universiteta [Bulletin of the Buryat State University] 3:31–35.
  12. Levshenkov, A. I., and L. E. Levshenkova. 2015. Gorenie smesey onievykh soley 5,5′-azotetrazola s okislitelyami [Combustion of mixtures of 5,5′-azotetrazole onium salts with oxidizers]. Chemical Physics and Mesoscopy 17:331–338.
  13. Han, Y. H., Y. Z. Yang, Z. M. Du, Z. M. Li, Q. Yao, Y. H. Wang, and Z. Y. Hu. 2016. The formulation design and performance test of gas generators based on guanidinium azotetrazolate. Propell. Explos. Pyrot. 42:276–282.
  14. Abe, M., T. Ogura, Ya. Miyata, K. Okamoto, Sh. Date, M. Kohga, and K. Hasue. 2008. Evaluation of gas generating ability of some tetrazoles and copper (II) oxide mixtures through closed vessel test and theoretical calculation. Sci. Technol. Energ. Ma. 69(6):183–190.
  15. Bucerius, K. M., F. W. Wasmann, and K. Menke. 1993. Stable, nitrogen-rich composition. Patent 5,198,046. 4 p.
  16. Petreykin, A. A., D. S. Antipov, A. A. Kunakov, L. E. Levshenkova, and A. I. Levshenkov. 2016. Razrabotka metodiki opredeleniya minimal’nykh initsiiruyushchikh zaryadov dlya nizkoplotnykh brizantnykh VV [Development of the method for determining the minimum initiation charges low density]. Uspekhi v khimii i khimicheskoy tekhnologii [Advances in Chemistry and Chemical Technology] 30(8):37–38.
  17. Antipov, D. S., A. A. Petreykin, A. A. Kunakov, L. E. Levshenkova, and A. I. Levshenkov. 2016. Detonatsionnaya sposobnost’ prostykh ammonalov v zaryadakh malykh diametrov [Capacity detonation binary ammonal in charge in charge of small diameter]. Uspekhi v khimii i khimicheskoy tekhnologii [Advances in Chemistry and Chemical Technology] 30(8):8–9.

Supplementary files

Supplementary Files
Action
1. JATS XML
2. AzT salts

Download (20KB)

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).