Email this article Combustion mechanism of perchlorates of methyl ammonium derivatives
- Authors: Sinditskii V.P.1, Egorshev V.Y.1, Serushkin V.V.1, Chepurnoy A.O.1, Mikhaleva A.A.1
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Affiliations:
- D. I. Mendeleev University of Chemical Technology of Russia
- Issue: Vol 16, No 3 (2023)
- Pages: 93-99
- Section: Articles
- URL: https://journal-vniispk.ru/2305-9117/article/view/289636
- DOI: https://doi.org/10.30826/CE23160309
- EDN: https://elibrary.ru/PBUOBC
- ID: 289636
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Abstract
Possible reasons for the unusual dependences of the burning rates on the pressure of onium salts of perchloric acid with methylamines are considered. It is shown that combustion of perchlorates of methyl ammonium derivatives is formed from the competition of precesses in the gas and condensed phases. In the implementation of the gas-phase combustion mechanism, very large evaporation enthalpies of salts play a huge role in the stability of salt combustion. The process of salt evaporation also affects the condensed-phase mechanism through high dissociation (surface) temperatures.
About the authors
Valery P. Sinditskii
D. I. Mendeleev University of Chemical Technology of Russia
Author for correspondence.
Email: vps@muctr.ru
Doctor of Science in chemistry, professor, dean, Chemical Engineering Department
Russian Federation, MoscowViacheslav Yu. Egorshev
D. I. Mendeleev University of Chemical Technology of Russia
Email: egorshev@yahoo.com
senior lecturer, Department of Chemistry and Technology of Organic Nitrogen Compounds
Russian Federation, MoscowValery V. Serushkin
D. I. Mendeleev University of Chemical Technology of Russia
Email: serushkin.v.v@muctr.ru
Candidate of Science in technology, professor, Department of Chemistry and Technology of Organic Nitrogen Compounds
Russian Federation, MoscowAleksey O. Chepurnoy
D. I. Mendeleev University of Chemical Technology of Russia
Email: chepurnoi.a.o@muctr.ru
engineer, Department of Chemistry and Technology of Organic Nitrogen Compounds
Russian Federation, MoscowAlena A. Mikhaleva
D. I. Mendeleev University of Chemical Technology of Russia
Email: mixal1996@yandex.ru
student, Department of Chemistry and Technology of Organic Nitrogen Compounds
Russian Federation, MoscowReferences
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