Enviar artigo por via de e-mail Enthalpy of formation of the trinitromethyl group
- Autores: Miroshnichenko E.A.1, Kon’kova Т.S.1, Shastin A.V.2, Vorob’ev A.B.1, Inozemtsev J.O.1, Inozemtsev A.V.1, Matyushin Y.N.1, Korsunskiy B.L.1,2
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Afiliações:
- N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
- Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
- Edição: Volume 16, Nº 3 (2023)
- Páginas: 124-130
- Seção: Articles
- URL: https://journal-vniispk.ru/2305-9117/article/view/290014
- DOI: https://doi.org/10.30826/CE23160312
- EDN: https://elibrary.ru/RWYFCC
- ID: 290014
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Resumo
The enthalpies of combustion and enthalpies of formation of three trinitromethyl derivatives of 1,3,5-triazine were determined by the calorimetric method. The data obtained can be used for calculating the energy capabilities of related compounds by the method of replacing functional groups. The thermochemical characteristics of trinitromethyl groups from 1,3,5-triazine derivatives are compared with the corresponding properties of these groups in azoles and nitroalkanes.
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Sobre autores
Eugeny Miroshnichenko
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: eamir02@mail.ru
Doctor of Science in chemistry, chief research scientist
Rússia, MoscowТatiana Kon’kova
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: tas-kon@mail.ru
Doctor of Science in chemistry, chief research scientist
Rússia, MoscowAleksey Shastin
Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
Email: shastin@icp.ac.ru
Doctor of Science in chemistry, leading research scientist
Rússia, Chernogolovka, Moscow RegionAlexey Vorob’ev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
Candidate of Science in technology, senior research scientist
Rússia, MoscowJaroslav Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
senior research scientist
Rússia, MoscowAlexey Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
research scientist
Rússia, MoscowYuriy Matyushin
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: ynm07@mail.ru
Doctor of Science in technology, head of laboratory
Rússia, MoscowBoris Korsunskiy
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences; Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
Email: vectr1@yandex.ru
Doctor of Science in chemistry, chief research scientist
Moscow; Chernogolovka, Moscow RegionBibliografia
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- Shastin, A. V., T. I. Godovikova, S. P. Golova, L. I. Khmel’nitskii, and B. L. Korsunskii. 1995. Nucleophilic substitution reactions of 2,4,6-tris(trinitromethyl)-1,3,5-triazine. 2. Interaction of 2,4,6-tris(trinitromethyl)-1,3,5-triazine with primary amines and hexamethyldisilazane. Chem. Heterocyc. Compd. 31:601–609. doi: 10.1007/BF01166338.
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