Investigation properties of waste from the chemical and metallurgical industries to assess the possibility of their use in concrete production

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Abstract

The investigation was conducted on waste from the chemical industry in the form of carbide silt and metallurgical industry in the form of microsilica. For the study, X-ray phase analysis used on a Shimadzu XRD-7000 diffractometer in Cu Kα radiation. Electron microscopic studies were carried out according to GOST R ISO 22309-2015 on a Tescan Vega III SBH electron microscope with an integrated Oxford X-Act energy-dispersive microanalysis system. The Co standard (MAC, reg. no. 9941 Co) and a cassette of standard samples (MAC, reg. no. 11192) were used as samples. Samples were prepared at the Quorum Q150RES spraying station. The amount of raw sludge components was calculated taking into account the preservation of the saturation coefficient and modular characteristics of the cement plant. The calculation of the raw mix consisted in determining the ratios between its components based on the chemical composition of the raw materials and the specified characteristics of the clinker. The possibility is shown and the limits of carbide silt input are determined for use as a lime component of raw sludge in obtaining cement clinker. The possibility of adjusting the lime component of raw sludge by using microsilica is established, which will allow maintaining a balance in silicon content. The identity in the formation of the main clinker phases formed during sludge firing for the pilot sample and the sample made from the enterprise sludge is proven by the X-ray method. Cement of the CEM-II/A22.5N brand was obtained in laboratory conditions, the properties of which correspond to the properties of cement of the industrial enterprise. It is shown that the use of carbide silt and microsilica in the cement industry will allow not only to use them as raw materials, but also to improve the environmental situation in the territory adjacent to these enterprises.

About the authors

B. P Kulikov

Siberian Federal University

ORCID iD: 0009-0002-2566-9934

I. V Tarasov

Siberian Federal University

ORCID iD: 0000-0003-3059-501X

A. I Bezrukikh

Siberian Federal University

ORCID iD: 0000-0002-0448-9793

I. L Konstantinov

Siberian Federal University

ORCID iD: 0000-0001-6802-5202

D. S Voroshilov

Siberian Federal University

ORCID iD: 0000-0002-1406-3665

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