Vol 58, No 1 (2018)

New oceanographic observations in the period 1990–2015 revealed significant salinity variations in the Oyashio Current. In the last 26 years, the salinity of the upper layer decreased by 0.2 PSU. The most rapid changes in salinity and temperature have been observed in the last five years. The time series of salinity measurements is characterized by the high-amplitude fluctuations synchronized with the lunar nodal cycle (18.6 years); i.e., high salinity is observed in the period of strong tidal currents. Modulation of diurnal tidal currents with the K₁ and O₁ periods in the lunar nodal cycle is significant [8, 9]. The amplitude was maximal in 1988 and 2006 and minimal in 1997 and 2015. The characteristics of tidal currents in the Oyashio Current and Sea of Okhotsk are considered based on available data of drifting buoys over the Kruzenshtern and Kashevarov banks. The amplitude of salinity variations synchronized with the lunar cycle is approximately 0.1 PSU; therefore, it has made a significant contribution to the salinity decrease in recent years.

The effect of seawater movement through the Kerch Strait for extreme deviations in the level and speed of currents in the Sea of Azov caused by the action of climate wind fields has been studied using the Princeton ocean model (POM), a general three-dimensional nonlinear model of ocean circulation. Formation of the water flow through the strait is caused by the long-term action of the same type of atmospheric processes. The features of the water dynamics under conditions of changing intensity and active wind direction have been studied. Numerical experiments were carried out for two versions of model Sea of Azov basins: closed (without the Kerch Strait) and with a fluid boundary located in the Black Sea. The simulation results have shown that allowance for the strait leads to a significant change in the velocities of steady currents and level deviations at wind speeds greater than 5 m/s. The most significant effect on the parameters of steady-state movements is exerted by the speed of the wind that generates them; allowance for water exchange through the strait is less important. Analysis of the directions of atmospheric circulation has revealed that the response generated by the movement of water through the strait is most pronounced when a southeast wind is acting.

Biogeochemical structures of three permanently stratified waterbodies were studied: a sea water basin (the Black Sea), an estuary (Hunnbunn fjord), and a freshwater lake (Nordbytjernet), with focus on the distributions of methylmercury (MeHg) and total mercury (THg). THg concentrations were similar in the sea water basin (0.2–1.8 ng/L) and the freshwater lake (0.8–1.2 ng/L), but significantly higher in the estuary (0.6–9.4 ng/L). An increase in the MeHg concentration and MeHg/THg ratio were found in the redox zone in all three basins, indicating bacterial production of MeHg in the aqueous phase. In the lake and estuary, the maximum MeHg concentration and MeHg/THg ratio were found in samples located closest to the bottom sediments, likely due to the formation of MeHg in surface sediments and subsequent diffusion to the overlying waters.

The shells of the chambered nautilus (Nautilus pompilius) are studied by X-ray structure analysis (XRD) and electron microscopy (SEM and TEM). The shell structure is examined in a nanometer scale using XRD and synchrotron-based small angle X-ray scattering (SAXS). The mineral composition of shells includes 98–99 wt % aragonite, ~1 wt % organic substance (conchiolin), 1 wt % strontianite, and 0.5 wt % calcite. Trace elements comprise Na, Mg, Al, K, Si, Fe, P, S, Zn, Sr, Ba, and Cl. The laminated layers are composed of aragonite crystals with a width of 5–10 μm and a thickness of 0.5–1 μm; the prismatic layers, with a length of 7–12 μm long and a width of 1–3 μm. According to XRD and SAXS assays, the aragonite layers are formed of flawless monocrystals lacking any internal structuring. The shell conchiolin is a polymer formed of a system of parallel fibers folded with a step of approximately 100 nm without longitudinal structuring. Presumably, the unique structure of the nautilus shells has determined the existence of Nautiloidea over 500 Ma and their preservation as fossils for over 100 Ma.

The data on the isotopic composition of particulate organic carbon (δ¹³C_POC) in the Caspian Sea water in summer–autumn 2008, 2010, 2012, and 2013 are discussed in the paper. These data allowed as to reveal the predominant genesis of organic carbon in suspended particulate matter of the active seawater layer (from 0 to 40 m). The δ¹³C_POC =–27‰ (PDB) and δ¹³C_POC =–20.5‰ (PDB) values were taken as the reference data for terrigenous and planktonogenic organic matter, respectively. Seasonal (early summer, late summer, and autumn) variations in the composition of suspended particulate matter in the active sea layer were revealed. A shift of δ¹³C_POC towards greater values was seen in autumn (with a slight outburst in the development (bloom) of phytoplankton) in comparison with summer (with large accumulations and an extraordinary phytoplankton bloom confined to the thermocline area). The seasonal dynamics of autochthonous and allochthonous components in the suspended particulate matter of the Middle and Southern Caspian Sea was studied with the use of data on the concentration of particulate matter and chlorophyll a, the phytoplankton biomass and the POC content.

Iron–manganese formations and igneous rocks of submarine elevations in the Sea of Japan contain overlapping mineral phases (grains) with quite identical morphology, localization, and chemical composition. Most of the grains conform to oxides, intermetallic compounds, native elements, sulfides, and sulfates in terms of the set of nonferrous, noble, and certain other metals (Cu, Zn, Sn, Pb, Ni, Mo, Ag, Pd, and Pt). The main conclusion that postvolcanic hydrothermal fluids are the key sources of metals is based upon a comparison of the data of electron microprobe analysis of iron–manganese formations and igneous rocks dredged at the same submarine elevations in the Sea of Japan.

This study presents new geochemical and isotope data on igneous rocks of the Vetlovaya marginal sea paleobasin (part of the Late Mesozoic–Cenozoic margin of the northwestern Pacific). The results show that the rock complexes of this marginal sea basin comprise igneous rocks with geochemical compositions similar to those of normal oceanic tholeiites, enriched transitional tholeiites, and ocean island and back-arc basin basalts. Island-arc tholeiitic basalts are present only rarely. The specific geochemical signatures of these rocks are interpreted as being related to mantle heterogeneity and the geodynamic conditions in the basin.

The paper presents the results of a study on the geomorphic structure, tectonic setting, and volcanism of the volcanoes and volcanic ridges in the deep Central Basin of the Sea of Japan. The ridges rise 500–600 m above the acoustic basement of the basin. These ridges were formed on fragments of thinned continental crust along deep faults submeridionally crossing the Central Basin and the adjacent continental part of the Primorye. The morphostructures of the basin began to submerge below sea level in the Middle Miocene and reached their contemporary positions in the Pliocene. Volcanism in the Central Basin occurred mostly in the Middle Miocene–Pliocene and formed marginal-sea basaltoids with OIB (ocean island basalt) geochemical signatures indicating the lower-mantle plume origin of these rocks. The OIB signatures of basaltoids tend to be expressed better in the eastern part of the Central Basin, where juvenile oceanic crust has developed. The genesis of this crust is probably related to rising and melting of the Pacific superplume apophyse.

The basic approaches, methods, and procedures for collecting and analyzing samples of microplastics in a marine environment are briefly described.