Enantiospecific Sorption of L-Lysin by Molecularly Imprinted Sorbents Based on Methacrylic Acid and Ethylene Glycol Dimethacrylate
- 作者: Polyakova I.V.1, Pisarev O.A.1,2
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隶属关系:
- Institute of Macromolecular Compounds, Russian Academy of Sciences
- Peter the Great St. Petersburg Polytechnic University
- 期: 卷 55, 编号 2 (2019)
- 页面: 107-111
- 栏目: Article
- URL: https://journal-vniispk.ru/0003-6838/article/view/152805
- DOI: https://doi.org/10.1134/S0003683819010137
- ID: 152805
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详细
L-lysine-imprinted polymeric sorbents based on methacrylic acid and ethylene glycol dimethacrylate have been synthesized. The equilibrium and kinetics of amino acid sorption on the synthesized sorbents and control sorbent (a nonimprinted analog) are compared. It is shown that the enantioselective separation of the D,L-lysine racemic mixture was most effectively performed on polymeric sorbent synthesized in the presence of 6 mol % L-lysine. The amino acid was fixed on the surface layer of this sorbent at energy-equivalent, specific binding sites.
作者简介
I. Polyakova
Institute of Macromolecular Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: pol_irina_val@list.ru
俄罗斯联邦, St. Petersburg, 199004
O. Pisarev
Institute of Macromolecular Compounds, Russian Academy of Sciences; Peter the Great St. Petersburg Polytechnic University
Email: pol_irina_val@list.ru
俄罗斯联邦, St. Petersburg, 199004; St. Petersburg, 195251
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