Radiation synthesis of tetrafluoroethylene telomers in chlorosilanes and their use for modification of aluminoborosilicate glass fabric


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Abstract

The kinetics of radiation-initiated telomerization of tetrafluoroethylene in dichlorodimethylsilane and chlorotrimethylsilane have been studied, and the molecular structure and properties of the telomers have been revealed. It has been shown that the introduction of ~3.5 wt % product telomer into aluminoborosilicate glass fabric gives a fluorinated glass-reinforced polymer material with good hydrophobicity.

About the authors

G. A. Kichigina

Institute of Problems of Chemical Physics

Author for correspondence.
Email: kga@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

P. P. Kushch

Institute of Problems of Chemical Physics

Email: kga@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

D. P. Kiryukhin

Institute of Problems of Chemical Physics

Email: kga@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

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