High-symmetry polymorph of anhydrous disodium hydrogen phosphate


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A new Na2HPO4 polymorph was prepared with space group Fddd, Z = 8, a = 5.8426(3) Å, b = 9.7908(5) Å, c = 12.2673(5) Å. The crystal structure includes PO4 tetrahedra and Na atoms, each surrounded by six O atoms positioned in the corners of a heavily distorted octahedron. The proton is equiprobably disordered over the O atoms.

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N. Somov

Nizhny Novgorod State University

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Email: somov@phys.unn.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950

F. Chausov

Physicotechnical Institute, Ural Branch; Udmurt State University

Email: somov@phys.unn.ru
俄罗斯联邦, ul. Kirova 132, Izhevsk, Udmurt Republic, 426000; Universitetskaya ul. 1, Izhevsk, Udmurt Republic, 426034

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