Double complex [Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4: Synthesis and crystal structure


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Аннотация

[Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4 (I) has been synthesized by the reaction between MnCl2 · H2O, NH4[Cr(NH3)2(NCS)4] · 0.5H2O and 4-aminoantipyrine (C11H13N3O) in an aqueous solution, and its structure has been determined by IR spectroscopy and X-ray diffraction. Crystals of complex I are triclinic, space group \(P\bar 1\), Z = 1, a = 13.2378(5) Å, b = 15.7796(5) Å, c = 16.7703(6) Å, α = 83.194(2)°, β = 75.874(2)°, γ = 66.529(1)°, V = 3115.2(2) Å3, and ρcalcd = 1.407 g/cm3.

Авторлар туралы

T. Cherkasova

Kuzbass State Technical University

Хат алмасуға жауапты Автор.
Email: ctg.htnv@kuzstu.ru
Ресей, ul. Vesennyaya 28, Kemerovo, 650000

I. Bagryanskaya

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk National Research State University

Email: ctg.htnv@kuzstu.ru
Ресей, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090

N. Pervukhina

Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: ctg.htnv@kuzstu.ru
Ресей, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090

A. Vornakov

Kuzbass State Technical University

Email: ctg.htnv@kuzstu.ru
Ресей, ul. Vesennyaya 28, Kemerovo, 650000

E. Cherkasova

Kuzbass State Technical University

Email: ctg.htnv@kuzstu.ru
Ресей, ul. Vesennyaya 28, Kemerovo, 650000

N. Kuratieva

Novosibirsk National Research State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: ctg.htnv@kuzstu.ru
Ресей, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090

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