Email this article Cobalt(II) hexaiododimercurate(II) complex with ε-caprolactam: Synthesis and crystal structure
- Authors: Tikhomirova A.V.1, Bagryanskaya I.Y.2,3, Pervukhina N.V.4, Cherkasova T.G.1
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Affiliations:
- Kuzbass State Technical University
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 62, No 2 (2017)
- Pages: 187-190
- Section: Coordination Compounds
- URL: https://journal-vniispk.ru/0036-0236/article/view/167376
- DOI: https://doi.org/10.1134/S0036023617020206
- ID: 167376
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Abstract
The conditions of synthesis of a new binary complex salt [Co(Cpl)6][Hg2I6] (Cpl is ε-caprolactam ε-C6H11NO) have been developed, and its structure has been characterized. The salt crystallizes in triclinic system, space group \(P\bar 1\), a = 10.1078(4) Å, b = 12.2680(5) Å, c = 13.0782(5) Å, α = 62.872(2)°, β = 72.394(2)°, γ = 76.834(2)°, V = 1367.98(9) Å3, Z = 1, and ρcalc = 2.297 g/cm3. The structure is insular and consists of isolated ions.
About the authors
A. V. Tikhomirova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
I. Yu. Bagryanskaya
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
T. G. Cherkasova
Kuzbass State Technical University
Author for correspondence.
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
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