Low-temperature synthesis of highly ordered lithium-cobalt double phosphates with improved electrochemical characteristics in lithium nitrate melt

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Abstract

A low-temperature technique for preparation of highly dispersed powders of lithium-cobalt double phosphates with a highly ordered crystal lattice and a given morphology is proposed. The electrochemical performance and cyclic life of the obtained compounds are shown to exceed the respective characteristics of the known analogs. The proposed method can be extended to obtain a wide range of electrode materials for lithium-ion batteries with olivine structure.

About the authors

N. V. Zharov

Federal Research Center “Kola Scientific Center of the Russian Academy of Sciences”, I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Email: n.zharov@ksc.ru
Apatity, Russia

M. V. Maslova

Federal Research Center “Kola Scientific Center of the Russian Academy of Sciences”, I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Apatity, Russia

V. V. Semushin

Federal Research Center “Kola Scientific Center of the Russian Academy of Sciences”, I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials

Apatity, Russia

References

  1. Xinxin Z., Guangchuan L., Dan L. // RSC Adv. 2017. V. 7. P. 37588. https://doi.org/10.1039/C7RA04714B.
  2. Zülke A., Li Y., Keil P., et al. // Batteries & Supercaps. 2021. V. 4. № 6. P. 934. https://doi.org/10.1002/batt.202100046.
  3. Song, S., Peng, X., Huang, K., et al. // Nanoscale Res. Lett. 2020. V. 15. P. 110. https://doi.org/10.1186/s11671-020-03335-8.
  4. Yang X., Lin M., Zhen G., et al. // Adv. Funct. Mater. 2020. V. 30. P. 2004664. https://doi.org/10.1002/adfm.202004664.
  5. Lyu Y., Wu X., Wang K., et al. // Adv. Energy Mater. 2021. V. 11. P. 2000982. https://doi.org/10.1002/aenm.202000982.
  6. Tolganbek N., Yerkinbekova Y., Kalybekkyzy S., et al. // J. Alloys Compd. 2021. V. 882. P. 160. https://doi.org/10.1016/j.jallcom.2021.160774.
  7. Jiangtao H., Weiyuan H., Luyi Y., et al. // Nanoscale. 2020. V. 12. № 28. P. 15036. http://dx.doi.org/10.1039/D0NR03776A.
  8. Wani T.A., Suresh G. // J. Energy Storage. 2021. V. 44. P. 103. http://dx.doi.org/10.1016/j.est.2021.103307.
  9. Zhang M., Garcia-Araez N., Hector A. // J. Mater. Chem. A. 2018. V. 6. № 30. P. 14483. http://dx.doi.org/10.1039/C8TA04063J.
  10. Markevich E., Sharabi R., Gottlieb H., et al. // Electrochem. Commun. 2012. V. 15. № 1. P. 22. https://doi.org/10.1016/j.elecom.2011.11.014.
  11. Wu X., Meledina M., Tempel H., et al. // J. Power Sources. 2020. V. 450. P. 227. https://doi.org/10.1016/j.jpowsour.2020.227726.
  12. Wu X., Meledina M., Barthel J., et al. // Energy Storage Mater. 2019. V. 22. P. 138. https://doi.org/10.1016/j.ensm.2019.07.004.
  13. Hou Y., Chang K., Li B., et al. // Nano Res. 2018. V. 11. P. 2424. https://doi.org/10.1007/s12274-017-1864-0.
  14. Zhaojin L., Zhenzhen P., Hui Z., et al. // Nano Lett. 2016. V. 16. № 1. P. 795. https://doi.org/10.1021/acs.nanolett.5b04855.
  15. Murukanahally Kempaiah D., Quang T., Takaaki T., et al. // RSC Adv. 2014. V. 4. https://doi.org/10.1039/C4RA10689J.
  16. Zharov N.V., Maslova M.V., Ivanenko V.I., et al. // Russ. J. Phys. Chem. 2023. V. 97. P. 2529. https://doi.org/10.1134/S0036024423110365.
  17. Wu B., Xu H., Mu D., et al. // J. Power Sources. 2016. V. 304. P. 181. https://doi.org/10.1016/j.jpowsour.2015.11.023.
  18. Truong Q., Devaraju M.K., Ganbe Y., et al. // Sci Rep. 2014. V. 4. P. 3975. https://doi.org/10.1038/srep03975.
  19. Truong Q., Devaraju M.K., Honma I. // J. Mater. Chem. 2014. V. 2. P. 3975 https://doi.org/10.1039/C4TA03566F.
  20. Manzi, J.; Curcio, M.; Brutti, S. // Nanomater. 2015. V. 5. P. 2212. https://doi.org/10.3390/nano5042212.
  21. Maeyoshi Y., Miyamoto S., Noda Y., et al. // J. Power Sources. 2017. V. 337. P. 92. https://doi.org/10.1016/j.jpowsour.2016.10.106.
  22. Ludwig J., Marino C., Haering D., et al. // RSC Adv. 2016. V. 6. № . 86. P. 82984. https://dx.doi.org/10.1039/C6RA19767A.
  23. Örnek A. // J. Chem. Eng. 2018. V. 331. P. 501. https://doi.org/10.1016/j.cej.2017.09.007.
  24. Truong Q.D., Devaraju M.K., Tomai T., et al. // ACS Appl. Mater. Interfaces. 2013. V. 5. P. 26. https://doi.org/10.1021/am403018n.

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