Мақаланы E-mail арқылы жіберу Reaction operator in the main equation of spin chemistry
- Авторлар: Purtov P.A.1,2
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Мекемелер:
- Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Шығарылым: Том 43, № 2 (2024)
- Беттер: 3-8
- Бөлім: Элементарные физико-химические процессы
- URL: https://journal-vniispk.ru/0207-401X/article/view/259892
- DOI: https://doi.org/10.31857/S0207401X24020016
- EDN: https://elibrary.ru/WJASAT
- ID: 259892
Дәйексөз келтіру
Ашық рұқсат
Рұқсат берілді
Аннотация
In our previous works, using an exactly solvable model as an example, we demonstrated the validity of the reaction operator in the basic equation of spin chemistry. However, in these works, only recombination from the singlet state was considered. Although the general relations allowed us to consider the general case. In the present paper, such a general case is analyzed. The radical pair comes into contact in a mixed singlet-triplet state, and recombination proceeds from both the singlet and triplet states. The result obtained fully corresponds to the basic equation of spin chemistry.
Толық мәтін
Авторлар туралы
P. Purtov
Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Хат алмасуға жауапты Автор.
Email: purtov@kinetics.nsc.ru
Ресей, Novosibirsk; Novosibirsk
Әдебиет тізімі
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Қосымша файлдар
Ескертпе
Х Международная конференция им. В.В. Воеводского “Физика и химия элементарных химических процессов” (сентябрь 2022, Новосибирск, Россия).