Synthesis of Catalytically Active Cermet Membranes Using Combustion Processes for Small Power Plants


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Abstract

Porous cermet membranes with improved operating properties were synthesized by means of SHS with a reduction stage in the thermal explosion regime in vacuum from a mixture of powders of the PTYu alloy (95% N – 5% Al) + Co3O4. As a result porous cermet membranes with 10 – 20 nm Ni and Co nanoparticles in the surface layers of the pores were obtained. A prototype of a power plant with high mass/size cell-battery characteristics was developed: specific volume 3.3 liters/kW and 1.6 kg/kW.

About the authors

V. I. Uvarov

Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Author for correspondence.
Email: uvar@ism.ac.ru
Russian Federation, Chernogolovka

V. É. Loryan

Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Email: uvar@ism.ac.ru
Russian Federation, Chernogolovka

S. V. Uvarov

Institute of Structural Macrokinetics and Materials Science of the Russian Academy of Sciences (ISMAN)

Email: uvar@ism.ac.ru
Russian Federation, Chernogolovka

E. S. Lukin

D. I. Mendeleev Russian Chemical Technology University

Email: uvar@ism.ac.ru
Russian Federation, Moscow

M. V. Tsodikov

A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences

Email: uvar@ism.ac.ru
Russian Federation, Moscow

A. S. Fedotov

A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences

Email: uvar@ism.ac.ru
Russian Federation, Moscow

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