


Vol 75, No 5-6 (2018)
- Year: 2018
- Articles: 16
- URL: https://journal-vniispk.ru/0361-7610/issue/view/15257
Science for Glass Production
Mathematical Model of Temperature Field Dynamics in Complex Shaped Glass Articles During Firing
Abstract
Mathematical models of the dynamics of temperature fields during firing of complex shaped glass articles are presented for the example of container glass of cylindrical-conical and prismatic-cylindrical shapes. The critical sections corresponding to the minorant and majorant of the thermal field are shown. The results of computer modeling of the dynamics of the thermal fields of glass articles are presented.



Early Stages of Crystallization of Lanthanum-Borogermanate Glass by a Femtosecond Laser Beam
Abstract
Regions in the bulk of lanthanum borogermanate glass modified by a femtosecond laser beam were studied by means of optical microscopy and confocal Raman scattering (RS) spectroscopy. The obtained data show that, at the stages preceding the formation of an LaBGeO5 microcrystal, upon irradiation by a femtosecond beam in a certain interval of laser pulse energy germanium nanocrystals precipitate in the zone of local heating. The correlation between the conditions of laser irradiation leading to the appearance of germanium nanocrystals and the conditions ensuring with high probability the crystallization of phases of the low-temperature modification of lanthanum borate and stillwellite-like lanthanum borogermanate suggest that germanium nanocrystals can serve as nuclei for heterogeneous crystallization of LaBO3 and LaBGeO3.



Article
Comparative Studies of the Use of Calcium Borate and Colemanite in the Production of Type-E Glass Fiber
Abstract
Data from comparative analysis of the cooking and extraction properties of glass with the composition of type-E glass fiber with calcium colemanite and borate are presented. The physical and chemical properties of synthesized glasses based on calcium colemanite and borate are studied.



Calculation of the Thermal Homogeneity Index of Molten Glass in the Feed Channel of Glass-Forming Machines
Abstract
Analytical and empirical expressions are presented for calculating the index of thermal homogeneity of molten glass in the feed channel of glass-forming machines. The analytical expressions are tested for nine- and five-point temperature matrices.



Determination of the Stiffness Characteristics of Composite Fiberglass Supports
Abstract
An investigation of the stiffness characteristics of fiberglass supports with cone angle about 89° is presented. A method is proposed for determining the modulus of elasticity in tension and compression in longitudinal and transverse directions of a composite support. Experimental studies were performed for measuring the modulus of elasticity in longitudinal and transverse directions, and formulas and empirical methods for calculating the modulus of elasticity and Poisson’s ratio in the transverse direction are proposed. It is showing that the modulus of elasticity in tension exceeds the modulus of elasticity in compression.



Particulars of the Sol-Gel Synthesis of Titanium Oxide Micro- and Nanoparticles for Creating a Composite Hybrid Antireflection Coating on Float-Glass
Abstract
Sol-gel processes occurring during hydrolysis in the presence of the surfactant diethylamine were studied. It is shown that the rate of the hydrolysis of tetrabutoxytitanium with minimal water and in the presence of dimethylamine is determined by the competition between the process of condensation of TiO2 nanoparticles and the process of adsorption of dimethylamine on the surface of TiO2 particles.



Effect of a Coating Deposited on Foam Glass on the Ability to Absorb High-Frequency Electromagnetic Radiation
Abstract
The effect of a modified coating, deposited on the surface of foam glass, on the ability to absorb electromagnetic radiation in the high frequency range was studied. It was established that a coating obtained on the basis of a liquid glass composition with ilmenite with 3 μm particles improves the radio absorption characteristics of the foam glass. For 1.5% ilmenite concentration in the coating composition the absorption coefficient of foam glass increases four-fold at 120 GHz and two-fold at 260 GHz compared with uncoated foam glass.



Composition Development and Property Study of Alkali-Resistant Enamel for the Protection of Chemical Apparatus
Abstract
The compositions of enamels which were synthesized and investigated for CLTE compatibility with metal and for resistance to alkali solutions at high temperatures were sorted out and elaborated on the basis of a patent search and theoretical calculations of the physical and chemical properties. Frit with the ARF-1 composition showed the best characteristics in terms of resistance to alkali solutions. The rate of corrosion (alkali-resistance test temperature 80°C) of the enamel coating was only 0.015 g/(m2 · h), which is 20 times lower than the rate of corrosion of the chemically resistant enamel MK-5.



Equipment
Modern Trends in Batch and Cullet Charging Technology for Horseshoe-Flame Glass Furnaces
Abstract
Modern systems based on innovative charging machines for batch and cullet charging of regenerative glass furnaces with horseshoe flame direction are examined. It is noted that such charging machines used in combination with adaptive control algorithms not only reduce the emission of dust and nitrogen oxides into the ambient atmosphere but also make the glassmaking process more efficient.



At Enterprises and Institutes
Effect of Highly Disperse SiO2 Particles on the Sintering of Quartz Ceramic: Firing Regime Choice for Quartz Ceramic Articles and the Colloidal Component Concept
Abstract
The factors affecting the sintering process for quartz ceramic are examined. The dependence of the post-firing density of blanks on the properties of the quart glass based slip is analyzed. It is proposed that the content of the highly disperse SiO2 particles in the slip affects the properties of the ceramic material. The concept of a colloidal component is described. The particle-size distribution in the colloidal component is analyzed.



Electroflotation Extraction of Highly Disperse Titanium Dioxide TiO2 from Water Solutions of Electrolytes
Abstract
The electroflotation extraction of fine particles of TiO2 and Ti(OH)4 was studied. It was determined that in water solutions of electrolytes with pH = 2 – 12 electroflotation of TiO2 proceeds inefficiently: the degree of extraction is 10 – 15%. The degree of extraction is 25 – 30% in the presence of surfactants and 90 – 95% in the presence of surfactants and the coagulant Fe+5. Electroflotation of Ti(OH)4 proceeds efficiently: the degree of extraction at pH = 3 reaches 99%, the electroflotation time 5 – 10 min, and energy consumption 0.5 kW · h/m3 of solution.



Materials Processing
High-Efficiency Materials-Processing Technology Based on New Types of Diamond Tools
Abstract
Examples are presented of the successful application of new types of diamond tools for high-efficiency processing of a wide class of materials such as glass, ceramic, sapphire, semiconductor materials, and different metals. The advantages of a bonded diamond tool based on heat-conducting polymer composite are shown.



Annealing of Glassy and Ceramic Materials by Nanosecond Laser Pulses
Abstract
The effect of pulsed laser radiation on glassy and ceramic materials is examined within the scope of the dynamic uncoupled problem of thermoelasticity for a half-space. Analytical relations expressing the thermal strength criteria for materials are obtained with three temporal shapes of laser pulses of nanosecond duration, making it possible to determine non-destructive regimes of annealing. The impact of the temporal shape of a laser pulse on the annealing regimes of materials is shown. It is found that laser pulses with a steep leading edge and a protracted trailing edge give thermoelastic stress reduction in the material.



Wastes into Production
New High-Strength Building Materials Based on Metallurgy Wastes
Abstract
Firing and non-firing high-silica composite building materials based on quartz sand and blast-furnace slag that are distinguished by high strength and durability, high density, abrasion resistance, and frost resistance were developed. They are readily manufactured and environmentally friendly and can be produced using extensive raw materials resources with minimum energy consumption. The technological and operational properties of the obtained materials are studied and applications are recommended.



Science for Ceramic Production
Production of High-Density Bitstone Powder for Sintering Aluminum Oxide Based Ceramic
Abstract
The results of theoretical and experimental studies of methods for obtaining bitstone powder with relative density greater than 0.50 for subsequent sintering of high-density, aluminum oxide based, ceramic samples are presented. The indicated pressing density was achieved by picking the spherical fractional composition of corundum power based on known theoretical models of close regular and random packing of spheres of different size. The prospects for using the described methods in ceramic part fabrication technology are evaluated.



Coatings
Protection of Nichrome-Alloy Articles from High-Temperature Corrosion (Review)
Abstract
The results of an analysis of research on the development of compositions and methods of depositing high-temperature coatings to protect different metals and alloys are presented. It is shown that further development of heat-resistant sital ceramic coatings for protecting high-temperature nichrome steels and alloys is topical.


