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Vol 75, No 5-6 (2018)

Science for Glass Production

Mathematical Model of Temperature Field Dynamics in Complex Shaped Glass Articles During Firing

Rubanov V.G., Velichko D.V., Lutsenko O.V.

Abstract

Mathematical models of the dynamics of temperature fields during firing of complex shaped glass articles are presented for the example of container glass of cylindrical-conical and prismatic-cylindrical shapes. The critical sections corresponding to the minorant and majorant of the thermal field are shown. The results of computer modeling of the dynamics of the thermal fields of glass articles are presented.

Glass and Ceramics. 2018;75(5-6):171-176
pages 171-176 views

Early Stages of Crystallization of Lanthanum-Borogermanate Glass by a Femtosecond Laser Beam

Lipat’eva T.O., Lopatina E.V., Sigaev V.N., Lipat’ev A.S., Lotarev S.V.

Abstract

Regions in the bulk of lanthanum borogermanate glass modified by a femtosecond laser beam were studied by means of optical microscopy and confocal Raman scattering (RS) spectroscopy. The obtained data show that, at the stages preceding the formation of an LaBGeO5 microcrystal, upon irradiation by a femtosecond beam in a certain interval of laser pulse energy germanium nanocrystals precipitate in the zone of local heating. The correlation between the conditions of laser irradiation leading to the appearance of germanium nanocrystals and the conditions ensuring with high probability the crystallization of phases of the low-temperature modification of lanthanum borate and stillwellite-like lanthanum borogermanate suggest that germanium nanocrystals can serve as nuclei for heterogeneous crystallization of LaBO3 and LaBGeO3.

Glass and Ceramics. 2018;75(5-6):213-216
pages 213-216 views

Article

Comparative Studies of the Use of Calcium Borate and Colemanite in the Production of Type-E Glass Fiber

Zavarina S.V., Lebedeva N.A., Gorina I.N., Chukatkina A.A., Ovchinnikova N.I.

Abstract

Data from comparative analysis of the cooking and extraction properties of glass with the composition of type-E glass fiber with calcium colemanite and borate are presented. The physical and chemical properties of synthesized glasses based on calcium colemanite and borate are studied.

Glass and Ceramics. 2018;75(5-6):177-180
pages 177-180 views

Calculation of the Thermal Homogeneity Index of Molten Glass in the Feed Channel of Glass-Forming Machines

Dzyuzer V.Y.

Abstract

Analytical and empirical expressions are presented for calculating the index of thermal homogeneity of molten glass in the feed channel of glass-forming machines. The analytical expressions are tested for nine- and five-point temperature matrices.

Glass and Ceramics. 2018;75(5-6):181-183
pages 181-183 views

Determination of the Stiffness Characteristics of Composite Fiberglass Supports

Adishchev V.V., Zubkov A.S., Ivanov A.I., Mal’tsev V.V., Panichev A.Y.

Abstract

An investigation of the stiffness characteristics of fiberglass supports with cone angle about 89° is presented. A method is proposed for determining the modulus of elasticity in tension and compression in longitudinal and transverse directions of a composite support. Experimental studies were performed for measuring the modulus of elasticity in longitudinal and transverse directions, and formulas and empirical methods for calculating the modulus of elasticity and Poisson’s ratio in the transverse direction are proposed. It is showing that the modulus of elasticity in tension exceeds the modulus of elasticity in compression.

Glass and Ceramics. 2018;75(5-6):195-201
pages 195-201 views

Particulars of the Sol-Gel Synthesis of Titanium Oxide Micro- and Nanoparticles for Creating a Composite Hybrid Antireflection Coating on Float-Glass

Kosobudskii I.D., Ushakov N.M., Nikitina L.V., Zhimalov A.B., Akhmedova A.S.

Abstract

Sol-gel processes occurring during hydrolysis in the presence of the surfactant diethylamine were studied. It is shown that the rate of the hydrolysis of tetrabutoxytitanium with minimal water and in the presence of dimethylamine is determined by the competition between the process of condensation of TiO2 nanoparticles and the process of adsorption of dimethylamine on the surface of TiO2 particles.

Glass and Ceramics. 2018;75(5-6):217-221
pages 217-221 views

Effect of a Coating Deposited on Foam Glass on the Ability to Absorb High-Frequency Electromagnetic Radiation

Kaz’mina O.V., Suslyaev V.I., Dorozhkin K.V., Kaimonov M.R., Stebeneva V.I.

Abstract

The effect of a modified coating, deposited on the surface of foam glass, on the ability to absorb electromagnetic radiation in the high frequency range was studied. It was established that a coating obtained on the basis of a liquid glass composition with ilmenite with 3 μm particles improves the radio absorption characteristics of the foam glass. For 1.5% ilmenite concentration in the coating composition the absorption coefficient of foam glass increases four-fold at 120 GHz and two-fold at 260 GHz compared with uncoated foam glass.

Glass and Ceramics. 2018;75(5-6):230-233
pages 230-233 views

Composition Development and Property Study of Alkali-Resistant Enamel for the Protection of Chemical Apparatus

Izgagina D.A., Uglinskikh M.Y., Vlasova S.G.

Abstract

The compositions of enamels which were synthesized and investigated for CLTE compatibility with metal and for resistance to alkali solutions at high temperatures were sorted out and elaborated on the basis of a patent search and theoretical calculations of the physical and chemical properties. Frit with the ARF-1 composition showed the best characteristics in terms of resistance to alkali solutions. The rate of corrosion (alkali-resistance test temperature 80°C) of the enamel coating was only 0.015 g/(m2 · h), which is 20 times lower than the rate of corrosion of the chemically resistant enamel MK-5.

Glass and Ceramics. 2018;75(5-6):234-236
pages 234-236 views

Equipment

Modern Trends in Batch and Cullet Charging Technology for Horseshoe-Flame Glass Furnaces

Efremenkov V.V.

Abstract

Modern systems based on innovative charging machines for batch and cullet charging of regenerative glass furnaces with horseshoe flame direction are examined. It is noted that such charging machines used in combination with adaptive control algorithms not only reduce the emission of dust and nitrogen oxides into the ambient atmosphere but also make the glassmaking process more efficient.

Glass and Ceramics. 2018;75(5-6):184-189
pages 184-189 views

At Enterprises and Institutes

Effect of Highly Disperse SiO2 Particles on the Sintering of Quartz Ceramic: Firing Regime Choice for Quartz Ceramic Articles and the Colloidal Component Concept

Kharitonov D.V., Makarov N.A., Anashkina A.A., Motornova M.S.

Abstract

The factors affecting the sintering process for quartz ceramic are examined. The dependence of the post-firing density of blanks on the properties of the quart glass based slip is analyzed. It is proposed that the content of the highly disperse SiO2 particles in the slip affects the properties of the ceramic material. The concept of a colloidal component is described. The particle-size distribution in the colloidal component is analyzed.

Glass and Ceramics. 2018;75(5-6):190-194
pages 190-194 views

Electroflotation Extraction of Highly Disperse Titanium Dioxide TiO2 from Water Solutions of Electrolytes

Kolesnikov A.V., Savel’ev D.S., Kolesnikov V.A., Davydkova T.V.

Abstract

The electroflotation extraction of fine particles of TiO2 and Ti(OH)4 was studied. It was determined that in water solutions of electrolytes with pH = 2 – 12 electroflotation of TiO2 proceeds inefficiently: the degree of extraction is 10 – 15%. The degree of extraction is 25 – 30% in the presence of surfactants and 90 – 95% in the presence of surfactants and the coagulant Fe+5. Electroflotation of Ti(OH)4 proceeds efficiently: the degree of extraction at pH = 3 reaches 99%, the electroflotation time 5 – 10 min, and energy consumption 0.5 kW · h/m3 of solution.

Glass and Ceramics. 2018;75(5-6):237-241
pages 237-241 views

Materials Processing

High-Efficiency Materials-Processing Technology Based on New Types of Diamond Tools

Kondratenko V.S.

Abstract

Examples are presented of the successful application of new types of diamond tools for high-efficiency processing of a wide class of materials such as glass, ceramic, sapphire, semiconductor materials, and different metals. The advantages of a bonded diamond tool based on heat-conducting polymer composite are shown.

Glass and Ceramics. 2018;75(5-6):202-205
pages 202-205 views

Annealing of Glassy and Ceramic Materials by Nanosecond Laser Pulses

Kovalenko A.F.

Abstract

The effect of pulsed laser radiation on glassy and ceramic materials is examined within the scope of the dynamic uncoupled problem of thermoelasticity for a half-space. Analytical relations expressing the thermal strength criteria for materials are obtained with three temporal shapes of laser pulses of nanosecond duration, making it possible to determine non-destructive regimes of annealing. The impact of the temporal shape of a laser pulse on the annealing regimes of materials is shown. It is found that laser pulses with a steep leading edge and a protracted trailing edge give thermoelastic stress reduction in the material.

Glass and Ceramics. 2018;75(5-6):242-245
pages 242-245 views

Wastes into Production

New High-Strength Building Materials Based on Metallurgy Wastes

Klimenko N.N., Kolokol’chikov I.Y., Mikhailenko N.Y., Orlova L.A., Sigaev V.N.

Abstract

Firing and non-firing high-silica composite building materials based on quartz sand and blast-furnace slag that are distinguished by high strength and durability, high density, abrasion resistance, and frost resistance were developed. They are readily manufactured and environmentally friendly and can be produced using extensive raw materials resources with minimum energy consumption. The technological and operational properties of the obtained materials are studied and applications are recommended.

Glass and Ceramics. 2018;75(5-6):206-210
pages 206-210 views

Science for Ceramic Production

Production of High-Density Bitstone Powder for Sintering Aluminum Oxide Based Ceramic

Smirnov A.V., Tarasovskii V.P., Ponomarev S.G., Rybal’chenko V.V., Vasin A.A.

Abstract

The results of theoretical and experimental studies of methods for obtaining bitstone powder with relative density greater than 0.50 for subsequent sintering of high-density, aluminum oxide based, ceramic samples are presented. The indicated pressing density was achieved by picking the spherical fractional composition of corundum power based on known theoretical models of close regular and random packing of spheres of different size. The prospects for using the described methods in ceramic part fabrication technology are evaluated.

Glass and Ceramics. 2018;75(5-6):222-225
pages 222-225 views

Coatings

Protection of Nichrome-Alloy Articles from High-Temperature Corrosion (Review)

Min’ko N.I., Lazareva E.A.

Abstract

The results of an analysis of research on the development of compositions and methods of depositing high-temperature coatings to protect different metals and alloys are presented. It is shown that further development of heat-resistant sital ceramic coatings for protecting high-temperature nichrome steels and alloys is topical.

Glass and Ceramics. 2018;75(5-6):226-229
pages 226-229 views