


Vol 75, No 7-8 (2018)
- Year: 2018
- Articles: 16
- URL: https://journal-vniispk.ru/0361-7610/issue/view/15260
Science for the Glass Industry
Specifics of Heat-Transfer Through the Melting Tank Wall in a Glass Furnace
Abstract
Amethod was developed for performing engineering calculations of the thermal resistance of the glass layer at the wall that makes it possible, by taking account of the physical crux of the process of heat transfer in semi-transparent media, to secure accuracy and simplify the determination of the temperature regimes in the melting tank of a glass furnace.



Science for Ceramic Production
Investigation of the Properties of SiC–ZrB2-Based Ceramic Composite Materials Obtained by Spark Plasma Sintering
Abstract
Spark plasma sintering was used to obtain experimental samples of ceramic composite materials in the system SiC–ZrB2 with graphite and aluminum nitride as additives. The physical and mechanical properties of composites (density, strength in bending, hardness, cracking resistance) were studied as a function of the production temperature parameters. The microstructure of the materials was studied and x-ray spectral microanalysis was performed and the oxidation resistance of the obtained samples at 1500°C was determined.



Low-Temperature Co-Firing Ceramic Li2Zn3Ti4O12 Modified by Li2O–ZnO–B2O3 Eutectic Additive
Abstract
Amaterial sintering at temperature 950°C for the technology of low-temperature co-firing ceramic used in the production of electronic components was developed in the system Li2O–ZnO–TiO2. The effect and method of synthesizing the eutectic sintering additive content in the system Li2O–ZnO–B2O3 on the compaction process and the dielectric properties of the obtained material were studied. The developed ceramic is characterized by the permittivity ε = 17.7 and dielectric Q-factor 407 MHz.



Coatings
Porous Functional Coatings by Microarc Oxidation
Abstract
FGUP TsNII KM “Prometey” have proposed a new approach to creating porous functional ceramic coatings on the surface of steel by means of low-temperature heterophase transport combined with microarc oxidation (MAO). The adhesion of the coating to metal is at least 60 MPa. An intermediate layer of the coating contains nickel–aluminum intermetallide compounds and imparts mechanical strength during service at temperatures above 750°C. It is shown for the example of nickel that catalytic active substances with promoters can be deposited on the surface of porous coatings from solutions of their salts or hydroxides followed by decomposition as a result of heat-treatment; metal can also be deposited into the pores of a MAO coating.



Wastes into Production
Building Ceramic from Mining Wastes
Abstract
The possibility of using the mining industry wastes in the form of magnesium-silicate rock—troctolites—in the production of building ceramic is studied. It is shown that the introduction of troctolite into batch promotes the reduction of fire shrinkage and water absorption of ceramic samples. It is shown that a new structure of the ceramic material is formed during the firing process and determines the physical and mechanical properties of the obtained materials.



Structure Formation in Cellular Glass Based on Novocherkassk CHPP Ash-Slag Wastes
Abstract
The compositions and technological parameters for the synthesis of cellular glass based on the ash-slag wastes from the Novocherkassk CHPP (heat-insulation layer of a multilayer silicate composite heat-insulation-decorative material) have been developed. DTA, XPA, and electronic microscopy were used to determine the physical and chemical regularities of the high-temperature formation of the structure of a porous heat-insulation layer of a multilayer silicate composite heat-insulation-decorative material.



Raw Materials
Glass Sands of Rostov Oblast
Abstract
The results of a search for and study of glass sands in Rostov Oblast are presented. The geological structure of the mineral deposits is described and the outlook for finding glass-sand deposits is evaluated. The characteristics of an open and explored glass-sand deposit with reserves exceeding 15 × 106 tons are presented. The qualitative characteristics and technological schemes for enriching this sand to grade OVS-020-V are presented.



Investigation of the Physical Properties of HCl-Modified Zeolites in the Vanginskoe Deposit in Amur Oblast
Abstract
The results of studies of the physical properties of zeolite raw material from the Vanginskoe deposit in Amur Oblast are presented. The structural and adsorption properties of material modified by HCl were studied. It is shown that the use of a 0.5M solution increases adsorption.



At Enterprises and Institutes
Apparatus for Identifying Microcracks on the Inner Surface of Glazed Pipes
Abstract
Amethod of identifying cracks on the inner surface of a glazed coating on a pipe with aid of a flaw detector is examined. The technological scheme is presented and the principle of operation of the developed apparatus is presented. The electric resistance of cracks in the glazed coating of a pipe is determined in terms of the parameter readings of the apparatus. A calculation of the basic dimensions of cracks in coatings along the entire length of standard pipes is presented.



Modernized Glassy Phosphate Composition for Water Treatment
Abstract
Experimental results on the properties of a glassy phosphate composition modernized by copper-containing additives are presented. The compositions are intended for protecting the surfaces of many materials from salt deposits (scale) and metallic surfaces from corrosion as well as for treating water solutions of organic substances in order to prevent the formation and multiplication in them of putrefactive bacteria and bacteria participating in eutrophication (‘blooming’). The composition is recommended for complex treatment of water for technical and household use.



Article
Fiberglass Coating Technology for the Production of Water Attractions
Abstract
The properties of reinforced polymer composite materials based on different types of polymer binders and glass fiber fillers were studied. The recipe and production technology were developed for articles made from fiberglass. This technology is based on a spraying assembly from the Glas Craft Company, combined with a chopper—a high-output cutting machine from the Greco Company. It is shown that the spray technology for producing from fiberglass, based on polyester resins and glass roving, large-size modules of water slides and other attractions for pools and water parks is technically sound and economically efficient.



Research on the Development of High-Quality Aluminum Oxide Ceramic (Review). Part 1. Sintering with Additives, Reactive Sintering, Production of Reinforced Composites
Abstract
Home-grown dissertations on ceramics obtained from aluminum oxide and methods for obtaining them in the period from 2000 are reviewed. Fine construction-grade ceramic is predominantly studied. The emphasis is on technological aspects. The first part of the review includes the sintering of Al2O3 with the addition of heteroelement oxides, reactive sintering with the addition of aluminum, the production of cermets of the type Al2O3, and the production of reinforced composites with an aluminum oxide matrix.



Rheological Properties of Ceramic Bodies and the Physical-Mechanical Indices of Acid-Resistant Materials Based on Nano-Technogenic Wastes from Petroleum Chemistry and Non-Ferrous Metallurgy and on Pyrophyllite
Abstract
It is shown that the amount of aluminum-containing nanotechnogenic raw material based on non-ferrous metallurgy and pyrophyllite has a large effect on the structure and rheological properties of ceramic bodies in the production of acid-resistant materials. The use of nanotechnogenic raw material increases the physical and mechanical properties of ceramics for acid-resistant materials. Studies have shown that the presence of pores with isometric shape and oval closed porosity, unlike elongated (slit-shaped) pores, in ceramic materials impart mechanical strength to them.



Facing Tile with Granite Texture: Technology and Properties
Abstract
An energy-conserving technology for glass-ceramic facing tile simulating the texture and basic mechanical properties of granite (water absorption < 1% and strength in compression 60 – 70 MPa) was developed and tested in the laboratory. The raw material mix includes 70% mixed external cullet. The technological process is distinguished by a high degree of self-sufficiency and flexibility.



Biomaterials
Calcium Phosphate Ceramic in the System Ca(PO3)2–Ca2P2O7 Based on Powder Mixtures Containing Calcium Hydrophosphate
Abstract
Powder mixtures prepared by mechanical activation from synthetic hydrated acidic calcium phosphates Ca(H2PO4)2 · H2O and CaHPO4 · 2H2O were used to obtain resorbable ceramic in the system Ca (PO3)2–Ca2P2O7. The phase composition of the ceramic after firing in the interval 700 – 1000°C was represented by biocompatible and bioresorbable phases: calcium polyphosphate Ca(PO3)2, tromelite Ca4P6O19, and calcium pyrophosphate Ca2P2O7. The obtained materials can be used to fabricate resorbable implants for regenerative treatment of defects of bone tissue.



Tungsten-Containing Bioactive Radiocontrast Glass: Production and Properties
Abstract
A method is proposed for obtaining radiocontrast bioglass by pyrolysis of organic solutions containing tetraethoxysilane, tributyl phosphate, sodium oleate, and calcium oleate in turpentine and also an extract in a benzene solution of tri-n-octylamine. This method makes it possible to obtain tungsten-containing radiocontrast glass as a powder or coating on different porous carriers.


