Email this article Immobilized copper- and molybdenum-containing ionic liquids in oxidation of sulfides
- Authors: Tarkhanova I.G.1, Anisimov A.V.1, Verzhichinskaya S.V.2, Buryak A.K.3, Zelikman V.M.1, Gantman M.G.1
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Affiliations:
- Faculty of Chemistry
- Mendeleev University of Chemical Technology of Russia
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 56, No 2 (2016)
- Pages: 158-165
- Section: Article
- URL: https://journal-vniispk.ru/0965-5441/article/view/178446
- DOI: https://doi.org/10.1134/S0965544116020158
- ID: 178446
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Abstract
The synthesis and comparative analysis of catalytic properties of Cu- and Mo-containing ethylpropylimidazolium derivatives immobilized on silica-series mineral supports have been performed. The oxidation of diethyl sulfide and methyl phenyl sulfide with oxygen and hydrogen peroxide in a hydrocarbon medium has been studied as a model process. The catalyst based on ethylpropylimidazolium polymolybdates is the most active and stable in the oxidation of methyl phenyl sulfide.
About the authors
I. G. Tarkhanova
Faculty of Chemistry
Author for correspondence.
Email: itar_msu@mail.ru
Russian Federation, Moscow
A. V. Anisimov
Faculty of Chemistry
Email: itar_msu@mail.ru
Russian Federation, Moscow
S. V. Verzhichinskaya
Mendeleev University of Chemical Technology of Russia
Email: itar_msu@mail.ru
Russian Federation, Moscow
A. K. Buryak
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: itar_msu@mail.ru
Russian Federation, Moscow
V. M. Zelikman
Faculty of Chemistry
Email: itar_msu@mail.ru
Russian Federation, Moscow
M. G. Gantman
Faculty of Chemistry
Email: itar_msu@mail.ru
Russian Federation, Moscow
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