Dibenzo-18-crown-6 as a catalyst for  tert -butyl hydroperoxide decomposition

Kh. E. Kharlampidi; N. M. Nurullina; N. N. Batyrshin; V. I. Anisimova; I. A. Suvorova

doi:10.1134/S0965544116020080

Dibenzo-18-crown-6 as a catalyst for tert-butyl hydroperoxide decomposition

作者: Kharlampidi K.E.¹, Nurullina N.M.¹, Batyrshin N.N.¹, Anisimova V.I.¹, Suvorova I.A.¹
隶属关系:
1. Kazan National Research Technological University
期: 卷 56, 编号 2 (2016)
页面: 171-174
栏目: Article
URL: https://journal-vniispk.ru/0965-5441/article/view/178451
DOI: https://doi.org/10.1134/S0965544116020080
ID: 178451

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅存取

详细
作者简介
参考
补充文件
统计

详细

Degradation of tert-butyl hydroperoxide in chlorobenzene in the presence of dibenzo-18-crown-6 ether has been studied. It has been established and kinetically proven that the degradation is preceded by the formation of an intermediate complex of the hydroperoxide with the crown ether. The composition of the complex and thermodynamic and kinetic parameters of its formation and decomposition have been determined.