Resonance energy transfer in a dense array of II–VI quantum dots

Abstract

Förster resonance energy transfer in inhomogeneous dense arrays of epitaxial CdSe/ZnSe quantum dots is demonstrated by time- and space-resolved photoluminescence spectroscopy. The specific feature of this process is the dipole–dipole interaction between the ground exciton levels of small quantum dots and the excited levels of large dots. This interaction brings efficient energy collection and spectral selection of a limited number of emitters. Results of theoretical modeling of optical transitions in spheroidal quantum dots with a Gaussian potential profile agree with the observed features of optical spectra induced by the change of the dominant energy transfer mechanism.