Correlation of the properties of ionic conductivity–structure for the RbGaO2 solid electrolyte


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The crystal structure of rubidium gallate RbGaO2 in the temperature range of 300–853 K has been investigated using high-temperature neutron diffraction. The channels available for the motion of rubidium cations in the low-temperature and high-temperature modifications of RbGaO2 have been determined using the computer simulation with the TOPOS program. A correlation between the radius of the migration channel cross section and the rubidium cation conductivity has been established.

Sobre autores

N. Proskurnina

Institute of Metal Physics, Ural Branch

Autor responsável pela correspondência
Email: Proskurnina@imp.uran.ru
Rússia, ul. Sofii Kovalevskoi 18, Yekaterinburg, 620990

V. Voronin

Institute of Metal Physics, Ural Branch

Email: Proskurnina@imp.uran.ru
Rússia, ul. Sofii Kovalevskoi 18, Yekaterinburg, 620990

I. Berger

Institute of Solid State Chemistry, Ural Branch

Email: Proskurnina@imp.uran.ru
Rússia, ul. Pervomaiskaya 91, Yekaterinburg, 620990

G. Shekhtman

Institute of High Temperature Electrochemistry, Ural Branch

Email: Proskurnina@imp.uran.ru
Rússia, ul. Akademicheskaya 20, Yekaterinburg, 620990

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