Phase transitions of SC(NH2)2 ferroelectrics in Al2O3-based nanoporous matrices


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Abstract

Temperature dependences of the linear permittivity ε' and the third harmonic amplitude γ of composites prepared by introducing ferroelectrics SC(NH2)2 into matrices of porous aluminum oxide Al2O3 with pore sizes 60 and 100 nm are determined. It is found that temperature Tc of the ferroelectric phase transition and the temperature Ti of the phase transition from incommensurable phase to the paraphrase increase significantly. The transition shifts increase as pore diameters decrease.

About the authors

A. Yu. Milinskii

Blagoveshchensk State Pedagogical University

Author for correspondence.
Email: a.milinskiy@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000

S. V. Baryshnikov

Blagoveshchensk State Pedagogical University; Amur State University

Email: a.milinskiy@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000; Ignat’evskoe sh. 21, Blagoveshchensk, 675027

A. A. Antonov

Blagoveshchensk State Pedagogical University

Email: a.milinskiy@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000

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