Evaluation of lyophility of carbon materials for electrodes of supercapacitors


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The heats of wetting have been measured experimentally for some of the solvents used for the preparation of electrolytes of supercapacitors. For the first time, the heat of wetting has been measured for a new promising solvent—tributyl phosphate. Using acetonitrile as an example, the possible orientation of the molecule at the adsorbing surface has been investigated by the technique of surface-enhanced Raman scattering (SERS) (effect of giant enhancement of the scattering by a conducting surface). The calculated estimates have been obtained for the quantities found in the experiment.

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M. Kompan

Ioffe Institute

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Email: Kompan@mail.ioffe.ru
俄罗斯联邦, Politekhnicheskaya ul. 26, St. Petersburg, 194021

D. Agafonov

St. Petersburg State Technological Institute (Technical University)

Email: Kompan@mail.ioffe.ru
俄罗斯联邦, Moskovskii pr. 26, St. Petersburg, 190013

A. Bursian

Institute of Macromolecular Compounds

Email: Kompan@mail.ioffe.ru
俄罗斯联邦, Bolshoi pr. 31, St. Petersburg, 199004

D. Dmitriev

St. Petersburg State Technological Institute (Technical University)

Email: Kompan@mail.ioffe.ru
俄罗斯联邦, Moskovskii pr. 26, St. Petersburg, 190013

M. Mikryukova

St. Petersburg State Technological Institute (Technical University)

Email: Kompan@mail.ioffe.ru
俄罗斯联邦, Moskovskii pr. 26, St. Petersburg, 190013

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